Phase conjugation reflcction with efficiencies o f 400% for microsecond pulses and ~50% Tur picosecond pulses has been obtained in saturable absorber dye Solutions. The effect o f difTcrcnt solvcnls on thc gencration o f the thermal pitase grating involved was investigated.We ltave recently reported [1] phase-conjugation [2] with conversión efficiences of up to 50% in DODCI and other saturable absorbers obtained with picosecond pulses from a mode-locked dye láser. Phase-conjugation reflection with lower efficiency, has also been measured [3] in an intra-cavity saturable absorber dye cell in the experimental arrangement conunonly used for passive mode-locking of pulsed and CW dye lasers [4,5], Photoisomer effeets [6] in the saturable absorber dye were found [3] to be important in the phase-conjugation process, particularly when the láser was tuned to longer wavelengths. Martin and Hellwarth [7] have shown that thermally induced refractive Índex changes [8][9][10][11] were the dominant mechanism in a variety of liquids employed in a four-wave mixing process for image conversión from infrared to visible and more recently the influence of the thermal grating in phase conjugation was discussed by Heilweil et al. [12]. We have investigated the role played by thermal effeets in phase conjuga tion reflection of picosecond pulses from saturable absorbers. In particular, the influence of solvents with very different thermal properties have been investigat ed together with the time behaviour of the conjugated wave.The experimental set up (fíg. 1) is similar to that reported previously [1]. The essential improvement is the use of a fast electro-optic Pockels' cell shutter between the láser and the sample cell to select out a well defined portion of the dye láser pulse train. A fast piloto diode (ITL type FD 125), PD1, was used to trigger the Pockels' cell and similar photodiodes (PD2 and PD3) monitored the probe beam intensity (¡2) and the conjúgate wave intensity (/4). A flashlamp pumped passively mode-locked dye láser [4] generated ~1 .2 ps pulses of ~100 mJ energy. In both cases, the láser was tuned by an intra-cavity etalon. The láser beam was focussed into the dye cell by lens L (f= 40 cm) and divided by a glass beam splitter 0 030-4018/81/0000-0000/$ 02.50 ©North-Holland Publishing Company 67