This study shows how bioenergy potential and total greenhouse gas (GHG) balances of land-use change and agricultural intensifi cation can be modeled in an integrated way. The modeling framework is demonstrated for fi rst-and second-generation ethanol production in Ukraine for the timeframe 2010-2030 for two scenarios: a business as usual (BAU) scenario in which current trends in agricultural productivity are continued; and a progressive scenario, which projects a convergence of yield levels in Ukraine with Western Europe. The spatiotemporal development in land for food production is analyzed making use of the PCRaster Land Use Change (PLUC) model. The land-use projections serve as input for the analysis of the CO 2 , N 2 O, and CH 4 emissions related to changes in land use and agricultural management, as well as the abatement of GHG emissions by replacing fossil fuels with bioethanol production from wheat and switchgrass. This results in annual maps (1 km 2 resolution) of the different GHG emissions for the modeled timeframe. In the BAU scenario, the GHG emissions increase over time, whereas in the progressive scenario, a total cumulative GHG emission reduction of 0.8 Gt CO 2 -eq for wheat and 3.8 Gt CO 2 -eq for switchgrass could be achieved in 2030. When the available land is used for the re-growth of natural vegetation, 3.5 Gt CO 2 -eq could be accumulated. These emission reductions could increase when appropriate measures are taken. The spatiotemporal PLUC model + GHG module allows for spatiotemporal and integrated modeling of total GHG emissions of bioenergy production and intensifi cation of the agricultural sector. Some studies have integrally assessed the impacts of agricultural and use and LUCs on GHG emissions. [17][18][19][20] Popp et al. 21 and De Wit et al. 22 assessed the GHG emissions of bioenergy production including the emissions from agricultural intensifi cation spatially explicitly. Due to the scope of these studies (global, European), the assessments were made on an aggregated spatial level, which partly disregard the high spatial heterogeneity biophysical factors. In addition, these assessments are not temporally explicit and therefore ignore the development of carbon sequestration and GHG emissions over time.In this study, a dynamic model is developed to assess the developments in CO 2 , N 2 O, and CH 4 emissions temporally and spatially explicitly for the period 2010-2030, taking into account the emissions related to agricultural intensifi cation and LUC. Th e GHG model is developed as an additional module of the PLUC model.15 Th e emissions are diff erentiated for biophysical factors such as land use, climate, and soil, making use of the best quality spatial data available. Th e model is demonstrated for a case study in Ukraine in which agricultural production is intensifi ed and the abandoned agricultural land is used for energy crops.Wheat and switchgrass are selected as typical fi rst-and second-generation bioethanol crops, respectively. As reand aff orestation could off er ...