Learning motivation is an encouragement in students to be able to learn well, add skills and provide learning experiences. High learning motivation will improve learning outcomes. This research is quantitative research to determine students' learning motivation, student learning outcomes, and the relationship between learning motivation and learning outcomes in learning chemistry on Hydrocarbon material with the application of Chemsketch media. The research was conducted at SMAN 2 Merauke in Class XI IPA 1 with 28 students. The sampling technique used is simple random sampling. The research data was obtained by using learning outcomes tests and learning motivation questionnaires. The research data were analyzed descriptively and the results obtained were: (1) student learning outcomes with an average score of 81,86 with 25 students passed the test and 3 students not past the test, (2) students' learning motivation with an average score of 80, 86 with 11 people in the very high category and 17 people in the high category.Followed by quantitative data analysis to test the linearity of the data, the normality of the data, and the correlation between learning motivation and learning outcomes with the Pearson bivariate correlation test. After analyzing the results obtained that (1) there is a linear and significant relationship, (2) the data is normally distributed, (3) there is a significant relationship between learning motivation and learning outcomes.