The U.S. Environmental
Protection Agency estimates that
there are
over 3.2 million abandoned wells in the United States. Studies conducted
on gas emissions from abandoned wells have been limited to methane,
a powerful greenhouse gas, due to concerns regarding climate change.
However, volatile organic compounds (VOCs), including benzene, a known
human carcinogen, are known to be associated with upstream oil and
gas development and hence could also be released when methane is emitted
to the atmosphere. In this investigation, we analyze gas from 48 abandoned
wells in western Pennsylvania for fixed gases, light hydrocarbons,
and VOCs and estimate associated emission rates. We demonstrate that
(1) gas from abandoned wells contains VOCs, including benzene; (2)
VOCs are emitted from abandoned wells, the magnitude of which depends
on the flow rate and concentration of VOCs in the gas stream; and
(3) nearly one-quarter of abandoned wells are located within 100 m
of buildings, including residences, in Pennsylvania. Together, these
observations indicate that further investigation is necessary to determine
whether emissions from abandoned wells pose an inhalation risk to
people living, working, or congregating near abandoned wells.