Perfluoroalkylzinc Compounds. I. The Preparation and Properties of Perfluoroalkylzinc Halides^1,2

Liquid-vapor equilibria and interfacial properties of n-alkanes and perfluoroalkanes by molecular simulation

“…In order to make direct comparisons with the data given by Tsige et al for compounds with carbon number between 7 and 10, additional surfacetension values were generated between 300 K and the minimum temperature values for each compound as given in the L-V equilibrium calculations. The experimental data points for compounds with carbon number between 6 and 9 given in that work 37 38,39 the data point at 300 K falls below the experimental melting temperature of this compound, which may account for the discrepancy.…”

Fluorinated Organozinc Reagents

“…Similarly, the method could be extended to (CF 3 ) 2 CFI and CF 3 (CF 2 ) 4 I substrates 100,101 but CF 3 I failed to give the organozinc reagent under these conditions 100 . Generally, the protocol requires peroxide-free solvents to avoid significant formation of R f H and dilute solutions to limit dimerization.…”

High Energy Efficiency Air Conditioning

“…It is likely that small equilibrium amounts of CF 3 ZnI formed in the compressor oil, which explains the similar amounts of both iodide and zinc found in the compressor oil. In the absence of water, CF 3 ZnIwould remain stable and should not have any effect on the compressor or plumbing in such small concentrations.…”

“…It was the most volatile component detected, and has been observed in other tests after prolonged heating of CF 3 I with oils at very high temperatures. The flame ionization detector (FID) response factor for CF 3 H was conservatively assumed to be the same as CF 3 I, which has a relatively weak response. This assumption, taken with the peak area measured, would therefore overestimate the amount of CF 3 H present.…”