Dispersion of nanoparticles is one of the potential solutions to
improve the thermophysical properties of phase change (or transition)
materials (PCMs) and enhance the performance of latent thermal energy
storage (LTES) systems. The PCM ought to have a high latent heat of
fusion, and zero or negligible coefficient of thermal expansion. A
good PCM should have melting and solidification compatibility with
negligible or zero subcooling, and it should not react with the common
chemical reagents. The present known PCMs possess low thermal conductivity
that results into a longer solidification and melting time of PCMs.
In the past two decades, researchers have reported improved thermal
conductivity and heat-storing capacity of PCMs employing graphite
nanoparticles/fibers, carbon nanotubes/fibers, metal, and metal oxide
nanoparticles. This work reviews the reported experimental and numerical
studies describing the consequences of nanoparticle inclusions of
various shapes and sizes on the thermal properties of the PCMs. This
review attempts to make a consolidated database of the studies related
to nanoadditive inclusion into PCMs for various applications. Graphene
dispersed into PCM has resulted into 14 times thermal conductivity
enhancement. As far as metal oxide nanoparticles are concerned, TiO2 and Al2O3 nanoparticles outperformed
others. The compatibility between the nanoadditive and PCM is necessary
to tailor favorable thermal properties. This work reviews numerous
studies of different nanoparticle–PCM duos.