Luminescent solar concentrators (LSCs) are all-photonic,
semitransparent
solar devices with great potential in the emerging fields of building-integrated
photovoltaics and agrivoltaics. Over the past decade, particularly
with the advent of quantum dot (QD) LSCs, tremendous progress has
been made in terms of photovoltaic efficiency and device size by increasing
solar spectral coverage and suppressing reabsorption losses. Despite
these advances in LSC design, the effects of environmental conditions
such as rain, dust, and dirt deposits, which are ubiquitous in both
urban and agricultural environments, on LSC performance have been
largely overlooked. Here, we address these issues by systematically
investigating the environmental effects on the solar harvesting and
waveguiding capability of state-of-the-art QD-LSCs, namely, the presence
of airborne pollutants (dust), water droplets, and dried deposits.
Our results show that dust is unexpectedly insignificant for the waveguiding
of the concentrated luminescence and only reduces the LSC efficiency
through a shadowing effect when deposited on the outer surface, while
dust accumulation on the inner LSC side increases the output power
due to backscattering of transmitted sunlight. Water droplets, on
the other hand, do not dim the incident sunlight, but are detrimental
to waveguiding by forming an optical interface with the LSC. Finally,
dried deposits, which mimic the evaporation residues of heavy rain
or humidity, have the worst effect of all, combining shading and waveguide
losses. These results are relevant for the design of application-specific
surface functionalization/protection strategies real LSC modules.