In this paper, we studied the charmless B c → V V (V denotes the light ground SU(3) vector meson) decays within the framework of QCD factorization. In the evaluation, two different schemes for regulating the end-point divergence are adopted. One (scheme I) is to use parameterization model, which is usually employed in the QCD factorization approach; the other (scheme II) is based on the infrared finite gluon propagator of Cornwall prescription. It is found that, in the annihilation amplitudes, the end-point divergence appears only in the power-suppressed corrections related to the twist-3 distribution amplitudes of V -meson. The strength of annihilation amplitudes evaluated in scheme II is generally larger than the one in scheme I. Numerically, in the decay modes considered in this paper, the CKM-favored B c → ρ − ω, K * − K * 0 decays have the relatively large branching fractions, ∼ O(10 −7 ), and hence are hopeful to be first observed by the future experiments. In addition, all of the decay modes are dominated by the longitudinal polarization state; numerically,