pH Dependent formations of dinuclear molybdenum(V) and incomplete cubane molybdenum(IV) complexes with nitrilotriacetate

Zhou, Zhao‐Hui; Xu, Qiang; Lin, Jin; Ng, Seik-Weng

doi:10.1016/j.inoche.2007.09.006

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2010

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Cited by 8 publications

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“…The {Mo 2 O 4 } 2+ core (shown in Scheme 1) with d electrons localized in a Mo(V)−Mo(V) single bond appears as a recurrent structural motif in many contexts of molybdenum(V) coordination chemistry [1,2,3,4,5,6,7]. A group of high-nuclearity oxomolybdenum(V) complexes whose structures may be seen as the assemblies of two or more {Mo 2 O 4 } 2+ units has emerged in the past two decades [8].…”

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confidence: 99%

Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine

Modec

Zubieta

2010

Materials

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A mononuclear complex [MoOCl4(H2O)]− readily forms a metal−metal bonded {Mo2O4}2+ core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo2O4Cl2(Py)4] composition is isolated as a product. Solid state structures of two compounds containing this complex, [Mo2O4Cl2(Py)4]·2.25Py (1) and [Mo2O4Cl2(Py)4]·1.5PyHCl (2), were investigated by X-ray crystallography.

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