Phosphorene and Phosphorene‐Based Materials – Prospects for Future Applications

Batmunkh, Munkhbayar; Bat‐Erdene, Munkhjargal; Shapter, Joseph G.

doi:10.1002/adma.201602254

Cited by 438 publications

(331 citation statements)

References 362 publications

(527 reference statements)

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“…Therefore, analogous strategies have been developed toward the configuration of BP and conductive carbonaceous materials in most cases, such as BP/acetylene black composites [49] and BP-graphite composites, [33] since BP was first used as an anode aterial for LIBs in 2007. [54][55][56][57][58][59][60][61] In this review, recent advances of RP-and BP-based anode materials for LIBs and/or SIBs are comprehensively summarized. In 2013, simultaneously and independently, Kim et al [51] and Qian et al [28] reported the RP, for the first time, as an anode material for SIBs, which opens up a novel idea to the underlying ability of phosphorus-based materials for SIBs applications.…”

Section: Advanced Phosphorus-based Materials For Lithium/ Sodium-ion mentioning

confidence: 99%

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Wei

Zhang

et al. 2018

Advanced Energy Materials

173

128

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High‐performance and lost‐cost lithium‐ion and sodium‐ion batteries are highly desirable for a wide range of applications including portable electronic devices, transportation (e.g., electric vehicles, hybrid vehicles, etc.), and renewable energy storage systems. Great research efforts have been devoted to developing alternative anode materials with superior electrochemical properties since the anode materials used are closely related to the capacity and safety characteristics of the batteries. With the theoretical capacity of 2596 mA h g−1, phosphorus is considered to be the highest capacity anode material for sodium‐ion batteries and one of the most attractive anode materials for lithium‐ion batteries. This work provides a comprehensive study on the most recent advancements in the rational design of phosphorus‐based anode materials for both lithium‐ion and sodium‐ion batteries. The currently available approaches to phosphorus‐based composites along with their merits and challenges are summarized and discussed. Furthermore, some present underpinning issues and future prospects for the further development of advanced phosphorus‐based materials for energy storage/conversion systems are discussed.

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Section: Advanced Phosphorus-based Materials For Lithium/ Sodium-ion mentioning

confidence: 99%

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Wei

Zhang

et al. 2018

Advanced Energy Materials

173

128

View full text Add to dashboard Cite

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“…

nanomaterials have been discovered and extensively studied, such as metal oxides, [9] transition-metal dichalcogenides (TMDs), [10][11][12] layered double hydroxides (LDHs), [13,14] 2D covalent organic frameworks (COFs), [15,16] 2D metal-organic frameworks (MOFs), [17,18] silicene, [19] germanene, [20,21] black phosphorene, [22][23][24] arsenene, [25][26][27][28] stanene, [29] borophene, [30,31] carbon nitride, [32,33] hexagonal boron nitride, [34][35][36] and Mxene, [37][38][39] etc. As an emerging class of nanoscale materials, 2D nanomaterials show unprecedented properties that are unparalleled compared to their corresponding bulk materials, which gives these materials promising applications in a wide range of areas, including high-speed electronic and optical devices, actuators and sensors, energy conversion and storage devices, DNA sequencing, and so on.

…”

mentioning

confidence: 99%

Two‐Dimensional Metal Oxide Nanomaterials for Next‐Generation Rechargeable Batteries

et al. 2017

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The exponential increase in research focused on two-dimensional (2D) metal oxides has offered an unprecedented opportunity for their use in energy conversion and storage devices, especially for promising next-generation rechargeable batteries, such as lithium-ion batteries (LIBs) and sodium-ion batteries (NIBs), as well as some post-lithium batteries, including lithium-sulfur batteries, lithium-air batteries, etc. The introduction of well-designed 2D metal oxide nanomaterials into next-generation rechargeable batteries has significantly enhanced the performance of these energy-storage devices by providing higher chemically active interfaces, shortened ion-diffusion lengths, and improved in-plane carrier-/charge-transport kinetics, which have greatly promoted the development of nanotechnology and the practical application of rechargeable batteries. Here, the recent progress in the application of 2D metal oxide nanomaterials in a series of rechargeable LIBs, NIBs, and other post lithium-ion batteries is reviewed relatively comprehensively. Current opportunities and future challenges for the application of 2D nanomaterials in energy-storage devices to achieve high energy density, high power density, stable cyclability, etc. are summarized and outlined. It is believed that the integration of 2D metal oxide nanomaterials in these clean energy devices offers great opportunities to address challenges driven by increasing global energy demands.

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“…Two-dimensional (2D) nanomaterials, such as silicene [1][2][3][4] and phosphorene, [5][6][7] have become prominent in gas sensor applications in recent years.…”

Section: Introductionmentioning

confidence: 99%

Adsorption of gas molecules on a graphitic GaN sheet and its implications for molecule sensors

et al. 2017

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aMotivated by the recent realization of two-dimensional (2D) nanomaterials as gas sensors, we have investigated the adsorption of gas molecules (SO 2 , NO 2 , HCN, NH 3 , H 2 S, CO, NO, O 2 , H 2 , CO 2 , and H 2 O) on the graphitic GaN sheet (PL-GaN) using density functional theory calculations. It is found that among these gases, only SO 2 and NH 3 gas molecules are chemisorbed on the PL-GaN sheet with apparent charge transfer and reasonable adsorption energies. The electronic properties (especially the electric conductivity) of the PL-GaN sheet showed dramatic changes after the adsorption of NH 3 and SO 2 molecules. However, the strong adsorption of SO 2 on the PL-GaN sheet makes desorption difficult, which precludes its application to SO 2 sensors. Therefore, the PL-GaN sheet should be a highly sensitive and selective NH 3 sensor with short recovery time. Furthermore, the adsorption of NO (or NO 2 ) molecules introduces spin polarization in the PL-GaN sheet with a magnetic moment of about 1 m B , indicating that magnetic properties of the PL-GaN sheet are changed obviously. Based on the change of magnetic properties of the PL-GaN sheet before and after molecule adsorption, the PL-GaN sheet could be used as a highly selective magnetic gas sensor for NO and NO 2 detection.

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Phosphorene and Phosphorene‐Based Materials – Prospects for Future Applications

Cited by 438 publications

References 362 publications

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives

Two‐Dimensional Metal Oxide Nanomaterials for Next‐Generation Rechargeable Batteries

Adsorption of gas molecules on a graphitic GaN sheet and its implications for molecule sensors

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