2017
DOI: 10.1002/mame.201700512
|View full text |Cite
|
Sign up to set email alerts
|

Phosphorus‐Containing Polymer Flame Retardants for Aliphatic Polyesters

Abstract: Polyesters with 9,10‐dihydro‐9‐oxy‐10‐phosphaphenanthrene‐10‐oxide‐containing comonomers are synthesized aiming to improve the flame retardancy of aliphatic polyesters such as poly(butylene succinate) and poly(butylene sebacate). The influence of the chemical structure on the thermal decomposition and pyrolysis is examined using a combination of thermogravimetric analysis (TGA), TGA‐Fourier transform infrared (FTIR) spectroscopy, pyrolysis‐gas chromatography/mass spectrometry, and microscale combustion flow ca… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
2
1

Citation Types

1
12
0

Year Published

2019
2019
2023
2023

Publication Types

Select...
7

Relationship

0
7

Authors

Journals

citations
Cited by 16 publications
(13 citation statements)
references
References 41 publications
1
12
0
Order By: Relevance
“…ItaP, a DOPO-containing polyester which already showed good fire behavior but wasn't investigated in PLA yet, was also tested in order to compare the efficiency of the synthesized flame retardants. [30,31] Since the fire behavior depends not only on the mode of action of the flame retardants and their interaction with the polymeric matrix, but also strongly on physical phenomena like melt dripping which correlates to the viscosity of the melt, two PLAs with different melt viscosities are investigated. [37] The composition of the formulations and the results are represented in Table 3 for the PLA with low viscosity (MFR, g/10 min, 210 • C, 2.16 kg: 80) and Table 4 for the PLA with higher viscosity (MFR, g/10 min, 210 • C, 2.16 kg: 14).…”
Section: Burning Behavior Of the Flame Retardants In Plamentioning
confidence: 99%
See 1 more Smart Citation
“…ItaP, a DOPO-containing polyester which already showed good fire behavior but wasn't investigated in PLA yet, was also tested in order to compare the efficiency of the synthesized flame retardants. [30,31] Since the fire behavior depends not only on the mode of action of the flame retardants and their interaction with the polymeric matrix, but also strongly on physical phenomena like melt dripping which correlates to the viscosity of the melt, two PLAs with different melt viscosities are investigated. [37] The composition of the formulations and the results are represented in Table 3 for the PLA with low viscosity (MFR, g/10 min, 210 • C, 2.16 kg: 80) and Table 4 for the PLA with higher viscosity (MFR, g/10 min, 210 • C, 2.16 kg: 14).…”
Section: Burning Behavior Of the Flame Retardants In Plamentioning
confidence: 99%
“…ItaP is a biobased flame retardant polyester of the DOPO adduct of dimethyl itaconate and ethylene glycol, which already showed good flame retardant effects in various polyesters, but was not investigated in PLA yet. [30,31]…”
Section: Introductionmentioning
confidence: 99%
“…The experimental values corresponded to vinylic polymers, polyesters, polyarylates, poly(ether sulfone)s, aromatic polyamides, and aromatic polyimides, all comprising one or two DOPO‐derived substituent group within the repeat unit. Only experimental values of T g of aromatic polyimides appeared really far from the estimation (Figure ).…”
Section: Resultsmentioning
confidence: 99%
“…A reaction could not be observed under various conditions, in most cases the BPPO ring opened. For SU-BPPO and DMI-BPPO, the synthesis of oligomers with different diols, as outlined before for DOPO derivatives [38], was also examined (Table S2). These experiments were not successful and they showed ring opening of the BPPO phosphonate ring.…”
Section: Resultsmentioning
confidence: 99%