“…Generally, raw bitumen from the oil sands, which includes oil sands hydrocarbons and PACs, tends to be δ 13 C depleted (bitumen δ 13 C, −30.3‰) similar to the oil sands NA extract (Farwell et al submitted for publication), and would likely not contribute to the observed δ 13 C enrichment. Humic and fulvic acids will also be present in the oil sands extract, although these higher molecular weight (800 to 100,000 amu) compounds tend to be recalcitrant to biodegradation (Headley and McMartin 2004;Ressler et al 1999;Ma et al 2001;Choi et al 2004;Young et al 2005;Adani et al 2006). Recalcitrant acid substances have however, been reported to be 13 C enriched (δ 13 C, −25.6‰, St-Jean 2003) relative to bitumen and NAs.…”