2008
DOI: 10.1002/jctb.1919
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Photocatalytic degradation of methyl tert‐butyl ether (MTBE) in contaminated water by ZnO nanoparticles

Abstract: BACKGROUND: Over the past several decades methyl tert-butyl ether (MTBE) as additive to gasoline, intended to either boost ratings of fuel or to reduce air pollution, has been accepted worldwide. Since MTBE has high water solubility, the occurrence of fuel spills or leaks from underground storage tanks or transferring pipeline has led to the contamination of natural waters. In this study the degradation of aqueous MTBE at relatively high concentrations was investigated by a UV-visible/ZnO/H 2 O 2 photocatalyti… Show more

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Cited by 47 publications
(29 citation statements)
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“…In fact, ZnO is also an important semiconductor photocatalyst, because the wide direct band gap (3.37 eV) of ZnO is almost the same as that of TiO 2 (3.2 eV), and its photodegradation mechanism is similar to that of TiO 2 [2]. Despite the positive attributes of ZnO photocatalyst, however, there are some drawbacks associated with its use: (i) charge carrier recombination occurs very fast [3] and (ii) the large band gap does not allow the utilization of visible light [4]. One of the ways to overcome these problems is to modify ZnO by addition of another semiconductor.…”
Section: Introductionmentioning
confidence: 94%
“…In fact, ZnO is also an important semiconductor photocatalyst, because the wide direct band gap (3.37 eV) of ZnO is almost the same as that of TiO 2 (3.2 eV), and its photodegradation mechanism is similar to that of TiO 2 [2]. Despite the positive attributes of ZnO photocatalyst, however, there are some drawbacks associated with its use: (i) charge carrier recombination occurs very fast [3] and (ii) the large band gap does not allow the utilization of visible light [4]. One of the ways to overcome these problems is to modify ZnO by addition of another semiconductor.…”
Section: Introductionmentioning
confidence: 94%
“…Among these methods, the advanced oxidation process (AOP) seems to be more practical than other methods such as activated carbon adsorption, reverse osmosis, and air stripping. Biological treatment is applied for wastewater-containing biodegradable substances and non-toxic materials [10,11]. AOPs such as ozonation, UV/H 2 O 2 , UV/O 3 , Fe 2+ /H 2 O 2 , and UV/O 3 /H 2 O 2 are widely applied for the degradation of organic compounds in industrial wastewater and groundwater [12].…”
Section: Desalination and Water Treatmentmentioning
confidence: 99%
“…HRT is another important parameter for determining the efficiency of the absorption process. Several studies have been carried out on the removal of different pollutants from water or wastewater using ZnO nanoparticles [35,38,45,46], with a different HRTs, which shows that this parameter is related to the type of pollutant. Figure 3c shows the effect of HRT on the removal efficiency of antibiotics with ZnO nanoparticles.…”
Section: Zno Nanoparticlesmentioning
confidence: 99%