2010
DOI: 10.1016/j.jhazmat.2010.08.033
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Photocatalytic degradation of methylene blue by TiO2–Cu thin films: Theoretical and experimental study

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Cited by 99 publications
(30 citation statements)
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“…Nevertheless, the enhanced photocatalytic efficiency by Cu nanoparticles doping compared with pure TiO 2 film in our case (13.51% in 6 h) is relatively low in comparison with most of the reported metal-Nps/TiO 2 composite films [17,19,27,29]. This may result from the CueO bond formed at the interface of Cu and TiO 2 as mentioned above, which is adverse to the photogenerated carriers separation.…”
Section: Photocatalytic Activitycontrasting
confidence: 53%
See 1 more Smart Citation
“…Nevertheless, the enhanced photocatalytic efficiency by Cu nanoparticles doping compared with pure TiO 2 film in our case (13.51% in 6 h) is relatively low in comparison with most of the reported metal-Nps/TiO 2 composite films [17,19,27,29]. This may result from the CueO bond formed at the interface of Cu and TiO 2 as mentioned above, which is adverse to the photogenerated carriers separation.…”
Section: Photocatalytic Activitycontrasting
confidence: 53%
“…By comparison, the microstructural, optical absorption properties and photocatalytic activity of Cu nanoparticle embedded TiO 2 films is studied insufficiently due to the oxidative nature and diffusion to TiO 2 of Cu [19]. Our research group previously demonstrated the possibility of synthesizing Nps-Cu/SiO 2 multilayer films utilizing the double target alternate sputtering system [20], hence the same hardware setup is expected to prepare Cu nanoparticles embedded TiO 2 films in this paper.…”
Section: Introductionmentioning
confidence: 99%
“…1(b), it can be seen that the copper element is present in ZnO:Cu films but not in ZnO, just as expected. The peaks at 932.44 and 951.43 eV is corresponding to Cu 2p 3/2 and Cu 2p 1/2 , while the energy separation of 19 eV is the typical character of spin-orbit interaction [14]. From the AFM images of ZnO and ZnO:Cu films, as shown in Fig.…”
Section: Methodsmentioning
confidence: 96%
“…5) [42,43]. The formation of Ti 3+ in the Cu-TiO 2 /PU could be due to the effect of the Cu dopant, which defected the TiO 2 lattice.…”
Section: Resultsmentioning
confidence: 99%