Photochemical interaction of phosphine hydride complexes of molybdenum and tungsten with carbon monoxide

Determination of charge-transfer electron transitions in tungsten tetrahydride complexes stabilized by organophosphorus ligands by X-ray photoelectron and UV absorption spectra

“…I-~ For example, coordinationally unsaturated species form complexes with N~ that can efficiently reduce coordinated nitrogen to hydrazine under the action of HCI. !-3 Different phosphinecarbonyl complexes are obtained in an atmosphere of CO. 4 In benzene and cyclohexane, the solvent molecules are inserted into the metal--carbon bond, resulting in the oxidative addition products. 5 Coordinationatly unsaturated species formed during photolysis can also enter intramoleeular reactions of oxidative addition of aryl or alkyl substituents of phosphine ligands.…”