The potential for a dielectric thin-film stack to provide omnidirectional reflection (near unity reflectance for all polarization states and incidence angles, over a finite range of wavelengths) was recognized only recently. [1][2][3] Nevertheless, such one-dimensional omnidirectional dielectric reflectors (ODRs) can provide some of the functionality promised by three-dimensional photonic crystals, while being comparatively simple to fabricate. They have been applied to the construction of low-loss hollow-core fibers [4] and integrated waveguides, [5,6] and to increase the emissivity of light-emitting diodes (LEDs).[7]An ODR is predicated on a pair of compatible dielectric materials that have transparency in the wavelength range of interest and sufficiently different refractive indices. For example, if the lower index material has a refractive index of n ∼ 1.5, an omnidirectional stop band can arise when the higher index material has n ∼ 2.3 or greater. It is an experimental challenge to identify material combinations that satisfy the refractive-index requirement, while also enabling practical implementation of a thermomechanically robust, stable, and uniform multilayer stack. Typical ODRs reported to date [1,2,[8][9][10] have employed a glass or semiconductor substrate as a base. However, ODR-based fibers have also been developed [11,12] and the fabrication of substrateless planar ODR mirrors (for the mid-IR) was reported anecdotally. [13] Of related interest, freestanding polymer-based optical filters were conceived several decades ago.[14] Moreover, efficient wide-angle mirrors based on highly birefringent polymers [15] are commercially available [16] in sheets ca. 50 lm thick. Freestanding optical filters have numerous potential applications, including reflectors for flexible organic LEDs, [17] laminates or wraps for light recycling in displays, [16] membranes in optomechanical light modulators, [18] pellicle-type beam splitters and filters, and sails on spacecraft propelled by radiation pressure. [19] Key to these applications is the flexibility, toughness, and fracture resistance of polymers, even in micrometer-scale thin sheets. These same properties motivate research and development of flexible electronic [20] and photonic [21,22] circuitry, using organic and sufficiently thin inorganic films.In this Communication, we describe a straightforward process for fabricating compliant but mechanically tough freestanding mirrors using commercially available chalcogenide glass and polymer materials. High-refractive-index contrast (Dn ∼ 1) between the materials enables near-unity, omnidirectional reflection from membranes less than 3 lm thick. The reflectors were successfully laminated (using surface-tension forces) on various flat and curved surfaces. Even after handling, bending, and re-lamination, the optical response of the reflectors was in excellent agreement with theoretical predictions. Optical filter response can be customized by manually stacking pieces of the mirror, and optomechanical tuning by stretchi...