Piezoelectronics, as an efficient approach for energy conversion and sensing, have a far-reaching influence on energy harvesting, precise instruments, sensing, health monitoring and so on. A majority of the previous works on piezoelectronics concentrated on the materials that are applied at close to room temperatures. However, there is inadequate research on the materials for high-temperature piezoelectric applications, yet they also have important applications in the critical equipment of aeroengines and nuclear reactors in harsh and high-temperature conditions. In this review, we briefly introduce fundamental knowledge about the piezoelectric effect, and emphatically elucidate high-temperature piezoelectrics, involving: the typical piezoelectric materials operated in high temperatures, and the applications, limiting factors, prospects and challenges of piezoelectricity at high temperatures.