“…[1][2][3][4][5][6][7][8] BiFeO 3 (BFO) is one of the most studied lead free room temperature multiferroic perovskite oxide because of its fascinating physical properties; large polarization (90µC/cm 2 ), weak ferromagnetism, and optical bandgap (~2.67 eV) [9][10][11][12] lies in visible region, make it suitable multifunctional material for spintronics, data storage, sensors, and optoelectronic applications. [13][14][15][16][17] Recently, the single phase BFO thin films showed promising potential towards ferroelectric photovoltaic (Fe˗PV) application due to enhanced room temperature ferroelectricity and small optical bandgap. [17][18][19][20] Among other wide bandgap Fe˗PV materials (i.e., BaTiO 3 , LiNbO 3 and Pb(Zr,Ti)O 3 ), BFO exhibits large open circuit voltage (V OC ), tunable output, and switchable photodiode effect 6,[9][10][11] .…”