In
this paper, we successfully fabricated CuBi2O4 and nitrogen,cuprum-codoped carbon nanosheet (N,Cu–C)
heterostructure connected by Au nanoparticles, which was applied in
photoelectrochemical (PEC) water splitting for the first time. The
Au nanoparticle in situ decoration on the material surface was carried
out by simple photoreduction. Owing to the plasmon resonance effect
and low charge transfer resistance of Au nanoparticles, CuBi2O4/Au/N,Cu–C hybrids exhibited enhanced photocurrent
compared with traditional CuBi2O4 and CuBi2O4/N,Cu–C. Typically, the as-prepared photoelectrode
displayed an optimal photoelectric conversion (0.17%, at 0.4 V vs
RHE) and PEC photocurrent (0.31 mA cm–2, at 100
mW cm–2 and 0.5 V vs RHE) that is about 5 times
that of pure CuBi2O4. The enhanced PEC water
splitting ability can be mainly attributed to the N,Cu-codoped carbon
nanosheets as the passivation layer and Au nanoparticles as an electron
relay for electron transport and a plasmonic photosensitizer for increased
light absorption.