We examine the nature of the lowest-energy optical transition in high-quality ͑Ga,In͒Sb/GaSb quantum wells. Despite the weak electron-hole interaction existing in this system, we observe a distinct exciton resonance in absorption. From the analysis of this resonance, we determine the binding energy and the oscillator strength of the quantum-confined exciton. The coincidence of the photoluminescence peak with the absorption resonance demonstrates that the dominant radiative channel is excitonic. Finally, we show that the thermal quenching of luminescence is related to the thermionic emission of excitons out of the well.
͓S0163-1829͑97͒06707-6͔Semiconductor heterostructures based on narrow-gap materials have been the subject of increasing interest in recent years. 1 These efforts are motivated by the possibility to extend optical studies to the mid-infrared region, and to eventually achieve cw lasing in this spectral range. Most studies have been performed on ͑Ga,In͒As/InP and ͑Ga,In͒͑As,Sb͒/ GaSb heterostructures 2,3 for which high-quality samples have become available. An alternative materials system for this spectral range is ͑Ga,In͒Sb/GaSb ͑Refs. 4 and 5͒ the band gap of which ranges from 0.81 eV ͑GaSb͒ to 0.15 eV ͑InSb͒. Despite its potential, little knowledge has been acquired about the physical properties of this materials system. The main reason for this fact is the lack of high-quality samples as illustrated by the dominance of impurity-related emission in the photoluminescence spectra of ͑Ga,In͒Sb/GaSb strained quantum wells ͑QW's͒. 6,7 Here, we present a detailed spectroscopic study of the optical properties of high-quality ͑Ga,In͒Sb/GaSb QW's. We show that the optical response is dominated by free excitons in both absorption and emission. From the analysis of the absorption spectrum, we determine both the binding energy and the oscillator strength of the quantum-confined heavyhole exciton.We concentrate in our study on a sample consisting of five ͑Ga,In͒Sb QW's separated by GaSb barrier layers. The sample is grown by conventional solid source molecularbeam epitaxy ͑MBE͒ on GaSb͑001͒ substrate. Monomeric Sb, generated by thermal cracking of Sb 4 at 900°C, is used as the Sb source. During growth, the substrate temperature is set to 400°C and the V:III flux ratio is maintained at 1.8. Further details about the substrate preparation and the optimization of growth have been described elsewhere. 8 For the absorption measurements, we use a Fourier transform spectrometer with a resolution of 1.0 cm Ϫ1 . Photoluminescence ͑PL͒ spectra are recorded using a HeNe laser ͑ϭ632.8 nm͒ and a Kr laser ͑ϭ647.1 nm͒ for high excitation density measurements. The luminescence signal is detected with a liquid-nitrogen-cooled InSb detector.Before discussing the optical properties, we present in Fig. 1 the symmetrical ͑004͒ and asymmetrical ͑115͒ x-ray diffraction rocking curves ͑XRC's͒ of the investigated sample. The pronounced splitting of the substrate and buffer layer peaks is due to the unintentional incorporation of 0.5% A...