The major limitation of the photonic digitization schemes based on the phase-shifting of modulation transfer function lies in its relatively low bit resolution, which is log2(2N), where N is the number of optical channels or modulators. In this paper, we propose a novel photonic digitization scheme based on hierarchical quantization, which could greatly improve the system resolution with a relatively simple configuration. It is shown that 6N quantization levels, can be realized by using only three Mach-Zehnder modulators (MZMs) and a hierarchical quantization module (HQM) in the proposed scheme. By adjusting the fine quantization module inside HQM, the system resolution can be enhanced greatly. A proof-of-concept experiment is implemented, which fully verifies the correctness of the approach. Since simpler configuration and higher resolution are achieved, the proposed scheme provides a promising solution for high-performance photonic analog-to-digital conversion.INDEX TERMS analog-to-digital conversion, hierarchical quantization, ENOB.