Photopolymerizable liquid encapsulants for microelectronic devices: Thermal and mechanical properties of systems with reduced in‐mold cure times

Abstract

Photopolymerizable liquid encapsulants (PLEs) for microelectronic devices may offer important advantages over traditional transfer molding compounds, including reduced in-mold cure times, lower thermal stresses, and reduced wire sweep. In this contribution, we discuss an encapsulation process based upon a low viscosity resin that cures rapidly upon exposure to UV light. These highly filled PLEs are comprised of an epoxy novolac-based vinyl ester resin (ϳ25 wt %), fused silica filler (70 -74 wt %), photoinitiator, silane coupling agent, and, in some cases, a thermal initiator. We have characterized the material properties (flexural strength and modulus, coefficient of thermal expansion, glass transition temperature, and thermal stress parameter) of PLEs cured with UV illumination times of 60, 90, and 120 s, as well as, the thermal conductivity and adhesive peel strength of PLEs photocured for 90 s. In addition, we investigated the effect of the fused silica loading and the initiation scheme on these properties. The results indicate that the PLEs are very promising for microelectronic encapsulation. These liquid encapsulants cure (to an ejectable hardness) in 1 min for an initiating light intensity of 200 mW/cm 2 , and exhibit appropriate values for the thermal and mechanical properties listed above.

Cationic UV-Curing: Technology and Applications

“…Photopolymerization of thick (greater than 1 mm) layers of monomers has found several applications in the field of composites materials . In order to overcome the limit of the light‐intensity attenuation it is useful to increase light intensity; it is also desirable to have a low initiator concentration and use a photobleachable initiator, allowing light to pass through the system .…”

UV‐ignited frontal polymerization of an epoxy resin

“…Nevertheless, photocuring has recently found applications in the production of thick polymers and composites 7, 8. To effectively cure a thick section, the initiator system and wavelength must be carefully selected to ensure that light can effectively penetrate the sample.…”

Cationically UV-Cured Epoxy Composites

“…[100][101] Photo-polymerized composites materials in thick dimensions, thicker than 1 mm, have numerous applications. [102][103] In case of thick samples light attenuation is a downside of photopolymerization. Light attenuation implies decrease in the intensity of light because of photon absorption by photoinitiator.…”