It is known that the thermal properties of a material influence the temperature around it. Once heated, the rate at which a material transfers the absorbed heat into the surroundings is determined by the thermal effusivity (or thermal inertia) of the material, and it depends on the well-known thermal properties, thermal conductivity, and specific heat capacity. Since a direct measurement of these properties is rather difficult for thin biological specimens such as plant leaves, a photothermal technique is used to measure the thermal effusivity, thermal diffusivity, thermal conductivity, and specific heat capacity for a few representative species of plant leaves. Measurements have been carried out on fresh as well as dry leaves to estimate the differences in their properties. Thermal properties of plant leaves are compared with the corresponding properties of two materials abundant in the environment and discussed. The influence of thermal properties, particularly the thermal effusivity and specific heat capacity, of plant leaves on controlling the temperature of the environment around them is discussed.