We have grown and characterized crystals of BaTiO 3 double doped with Ce and Rh. This material has defect charge states that can easily be manipulated by illumination with different wavelengths of light and may have potential for nonvolatile holographic storage using a two-step, sensitized recording scheme. Electron paramagnetic resonance ͑EPR͒, photo-EPR, optical absorption, and light-induced optical-absorption measurements were used to identify the charge states, probe the electronic structure, and locate the ionization levels associated with the Ce and Rh centers relative to the band edges of the BaTiO 3 host. In addition, the effects of illumination at various wavelengths on the defect states were used to develop a qualitative sensitization model.