Photosensitizer‐catalyzed Addition Reactions of N‐α‐Trimethylsilyl‐N‐Alkylglycinates to Dimethyl Acetylenedicarboxylate

Synthesis and solubility properties of amine‐functionalized fulleropyrrolidines in organic solvents

“…From our recent study about single electron transfer (SET)-promoted photoaddition reactions of amine substrates to electron acceptors, we found that tertiary amines possessing both α-silyl and α-alkoxycarbonyl groups at the nitrogen atom could serve as efficient azomethine ylide precursors. Based on these observations, 16,23,24 firstly, α-silyl group tethered N-alkyl-(1a-1 g), N-benyzl-(1h-1 L), and N-phenethyl-(1m-1p) glycinate substrates were prepared (Figure 1).…”