1992
DOI: 10.1021/ja00033a022
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Photosynthetic water oxidation center: spin frustration in distorted cubane MnIVMnIII3 model complexes

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Cited by 183 publications
(104 citation statements)
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“…8). 16 One Mn atom is bridged to each of the other three Mn atoms by a carboxylate. These three Mn atoms are bridged by a three-coordinated Cl atom and are each coordinated to a Cl atom and an amine ligand.…”
Section: Sbu Descriptionsymentioning
confidence: 99%
“…8). 16 One Mn atom is bridged to each of the other three Mn atoms by a carboxylate. These three Mn atoms are bridged by a three-coordinated Cl atom and are each coordinated to a Cl atom and an amine ligand.…”
Section: Sbu Descriptionsymentioning
confidence: 99%
“…The data were fit assuming only the ground state is populated at these temperatures, using the methods described elsewhere 19,20 (24) Mn (5) O (106) 85.09 (13) O (18) Mn (10) O (76) 173.96 (14) Mn (5) O (24) Mn (6) 95.30(13) O (24) Mn (5) O (124) 91.26 (13) O (18) Mn (10) O (86) 90.16 (13) Mn (5) O (24) Mn (9) 124.24 (15) O (38) Mn (5) O (46) 86.93 (14) O (19) Mn (10) O (25) 95.88 (13) Mn (6) O (24) Mn (9) 134.50 (17) O (38) Mn (5) O (106) 90.36(13) Mn (1) O (17) 1.913 (4) Mn (4) O (21) 1.896(4) Mn (7) O (15) (2) O (15) 1.892 (4) Mn (5) O (40) 1.938 (4) Mn …”
Section: Description Of Structuresmentioning
confidence: 99%
“…Frequency-dependent M ′′ signals have been observed in the ac susceptibility studies of all Mn 12 SMMs and are considered a diagnostic signature of the SMM property. 2,4,20,21 In addition, ac magnetic susceptibility data can be employed to obtain the effective energy barrier (U eff ) for magnetization relaxation and even the spin of the ground state. 21 For these reasons, ac susceptibility studies were performed on complexes 5 and 6.…”
Section: Description Of Structuresmentioning
confidence: 99%
“…These anisotropic high spin molecules exhibit original magnetic properties such as single molecule magnet behaviour [12,13,14,15,16,17] (long relaxation time for the magnetisation below a so-called blocking temperature, T B ) or magnetic quantum tunnelling effect [18,19]. Our research approach is devoted to the synthesis of such complexes in order to get single molecule.…”
Section: Introductionmentioning
confidence: 99%