Topological semimetals can be classified by the connectivity and dimensionality of the band crossing in momentum space. The band crossings of a Dirac, Weyl, or an unconventional fermion semimetal are zero-dimensional (0D) points, whereas the band crossings of a nodal-line semimetal are one-dimensional (1D) closed loops. Here we propose that the presence of perpendicular crystalline mirror planes can protect three-dimensional (3D) band crossings characterized by nontrivial links such as a Hopf link or a coupled-chain, giving rise to a variety of new types of topological semimetals. We show that the nontrivial winding number protects topological surface states distinct from those in previously known topological semimetals with a vanishing spin-orbit interaction. We also show that these nontrivial links can be engineered by tuning the mirror eigenvalues associated with the perpendicular mirror planes. Using first-principles band structure calculations, we predict the ferromagnetic full Heusler compound Co2MnGa as a candidate. Both Hopf link and chain-like bulk band crossings and unconventional topological surface states are identified.Since the discovery of Dirac and Weyl semimetals [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19][20], topological semimetals have emerged as an active frontier in condensed matter physics. Their unique topological properties are predicted to give rise to a wide range of exotic transport and optical phenomena [21][22][23][24][25][26][27][28][29][30][31][32][33][34][35][36][37]. By considering various rotational and mirror symmetries in both symmorphic and non-symmorphic contexts, researchers have predicted nodal-line semimetals [38] [48][49][50]. Despite this diversity, topological semimetals can be further classified and characterized by the dimensionality of their band crossings in the bulk Brillouin zone (BZ). In a Dirac/Weyl semimetal or an unconventional (higher-fold degenerate) fermion semimetal [41,[43][44][45][46], the conduction and valence bands cross at discrete points in the BZ. Therefore, the dimension of their band crossings is 0D. In a nodal-line semimetal [38], the conduction and valence bands touch along a closed loop, thus the dimension of its band crossing is 1D. In this letter, we propose a number of previously unidentified topological semimetals and identify a candidate material class for the experimental realization. They feature 3D band crossings characterized by nontrivial links such as a Hopf link or a coupled-chain enabled by perpendicular mirror planes. The Hopf link, which consists of two rings that pass through the center of each other, represents the simplest topologically nontrivial link. While originally studied in mathematics and other areas, recently, researchers have applied this concept into topological physics in order to construct novel topological insulators and superconductors [52][53][54], although the role of Hopf link is distinctly different from what is considered here. Here we apply this idea in metals and show that the c...