“…The thermoreflectance technique was first developed in the 1970s and 1980s, where continuous wave (CW) light sources were used for the heating and sensing. 49,50 With the advancement of pico-and femtosecond pulsed laser in the 1980s, this technique was widely used for studying non-equilibrium electron-phonon interaction, [51][52][53][54][55][56] coherent phonon transport, 27,[57][58][59][60][61] picosecond acoustics, [62][63][64][65][66][67][68][69][70][71][72] optical properties, [73][74][75] thermal expansion coefficient 76 and thermal transport properties of thin films 77,78 and interfaces. 40,41,43,44,46,47,[79][80][81][82][83][84][85] Among these, Paddock and Eesley 77 were the first to measure thermal diffusivity of metal films using picosecond transient thermoreflectance, and Humphrey Maris' group have done a series of original res...…”