The low-temperature sintering behavior of Pb(Zr 0.53 , Ti 0.47 ) O 3 -Sr(K 0.25 , Nb 0.75 )O 3 (PZT-SKN) piezoelectric ceramics with LiBiO 2 and CuO addition has been investigated. The addition of 6 wt% LiBiO 2 or 1 wt% LiBiO 2 11 wt% CuO promotes the sinterability of 0.98PZT-0.02SKN ceramics owing to the generation of a liquid phase, resulting in a reduction of sintering temperature by about 3001-3501C. The microstructure, dielectric, and piezoelectric properties of flux-sintered ceramics were examined and compared with materials conventionally sintered at 12501C. PZT-SKN ceramics with 1 wt% LiBiO 2 11 wt% CuO addition were sintered to high density at 9001C for 1 h. The resulting samples exhibited a high-field d 33 piezoelectric coefficient of 415 pm/V with a Curie temperature T c of around 3511C, dielectric constant e r of 1235, and planar coupling factor k p of 0.54. The reduced sintering temperature and short soaking time, together with the favorable dielectric and piezoelectric properties of the fluxed PZT-SKN ceramics, demonstrate the potential opportunity of integration with lowtemperature cofired ceramic materials and low-fire electrode materials for the multilayer piezoelectric transducer application.