The present paper is concerned with the piezoelectric properties and related parameters of the 2-2-type parallel-connected composites wherein rotations of the main crystallographic axes in ferroelectric single-crystal components are analysed. The composite consists of layers of two types that are regularly arranged along the non-polar axis. The Type I layer is a single-domain 0.63Pb(Mg1/3Nb2/3)O3-0.37PbTiO3 single crystal (either tetragonal in Composite I or orthorhombic in Composite II). The Type II layer is a Li2B4O7 single crystal / polyethylene medium with 0-3 connectivity. The composite as a whole is characterised by 2-0-2 connectivity, and the following parameters of the composite are studied by taking into account the polarisation orientation effect in the Type I layer and the microgeometry of the composite in the Type II layer: piezoelectric coefficients * 3 j d and * 3 j g and their hydrostatic analogs * h d and * h g , hydrostatic squared figure of merit * h d * h g , and piezoelectric anisotropy factors * 33 d / * 32 d and * 33 d / * 32 d . It is shown that large values of the studied piezoelectric coefficients, hydrostatic parameters and anisotropy factors make Composite II more preferable in comparison to Composite I for hydroacoustic, piezoelectric sensor and energy-harvesting applications.