“…ZnO is a wide direct band gap semiconductor of 3.374 eV at 300 K, having high thermal conductivity, electronic mobility, and large exciton binding energy of 60 meV. , Therefore, it has attracted a strongly increasing interest since it can be applied in electronic and optoelectronic devices including a field effect transistor, , nanogenerator, resistive switching, , gas sensor, − memory, , photodetector, − and piezoelectric diode. − For nanostructured ZnO with a very large surface-to-volume ratio and typical n-type properties, however, dangling bonds can induce quantities of acceptor-type surface states due to a breaking of lattice periodicity on its surface, resulting in a band bending upward and a carrier-depletion layer in the vicinity of surfaces, and correspondingly a surface barrier-related diode can be formed. ,, Moreover, high densities of surface states can give rise to Fermi-level pinning, and hence, its interface barrier is independent of metal work function and semiconductor electron affinity. For ZnO nanostructure-based devices with a high surface barrier, it is, therefore, difficult to conduct at a low operation bias, showing a high resistance state (HRS) ,,, In addition, quantities of defects, such as oxygen vacancy (V o ) and zinc interstitial (Zn i ), exist in ZnO lattice, resulting in the formation of traps with different levels.…”