In this article, we report on the deposition and characterization of Ga-doped ZnO (GZO) films prepared by thermal-mode (TM) and plasma-mode (PM) atomic layer deposition (ALD) techniques. The GZO films were post-processed by annealing, Zn driven-in, and Mg/Zn driven-in. The driven-in process was performed by rapid thermal diffusion using ZnSiO x or MgSiO x /ZnSiO x spinning-on dopant (SOD) source. The Zn driven-in process on TM-ALD GZO films can effectively alleviate the Zn loss and suppress the increase of resistivity. Furthermore, the Mg/Zn drive-in process of TM-ALD GZO films can effectively enhance the ultraviolet (UV) transmittance. For application to near-infrared region (NIR), the Zn driven-in process on PM-ALD GZO films can increase the carrier concentration and reduce the resistivity. The 380-nm ultraviolet (UV) InGaN/GaN light-emitting diodes (LEDs) with using Mg/Zn driven-in TM-ALD GZO film as a transparent conducting layer can enhance the light extraction from 0.74 to 1.87 mW at 20 mA. Besides, the 2.2-μm InGaAs PIN photodiodes (PDs) with using Zn driven-in PM-ALD GZO film as a window layer can significantly lower the dark current at 1 V from 1.1 × 10 −5 (1.4 × 10 −3 A/cm 2 ) to 5.2 × 10 −6 A (6.6 × 10 −4 A/cm 2 ).ZnO-based transparent conductive oxides (TCOs) have been extensively investigated due to its low resistivity, high transparency in the visible region, and low cost of ZnO. Group III elements (Al, Ga, and In) can be introduced into ZnO as the extrinsic dopants to enhance the conductivity significantly. 1 Ga-doped ZnO (GZO) films have been expected as one of the most promising ZnO-based TCOs because of the similar ionic radii between Ga 3+ dopant and Zn 2+ ion (and thus a small lattice deformation of ZnO), and the similar covalent bond lengths between Ga-O (1.92 Å) and Zn-O (1.97 Å). 2,3 GZO films have played an important role as the transparent electrode or current spreading layer for light-emitting diodes (LEDs) to improve the uniform current injection. 4 It can be also used as the window layer for solar cells or photodiodes (PDs) to reduce the dark current. The GZO films are also highly anticipated for the application of micro-optoelectro-mechanical systems (MOEMS). 5 There is no carrier-current drift in MOEMS, so it is expected to supply the uniform voltage into device with GZO films by the even air gap modulation.Recently, atomic layer deposition (ALD) has gained much attention because of advantages of large area deposition, smooth surface morphology, excellent uniformity, high step coverage, and high aspect ratio. 6 In particular; thickness and concentration of film could be controlled precisely and easily. We previously reported the as-grown GZO films with a sandwich structure deposited by thermal-mode (TM) and plasma-mode (PM) ALD techniques. 7 The TM-ALD GZO films exhibit lower resitivity but poorer transmittance in the near-infrared region (NIR), opposite to PM-ALD GZO films. Typical TM-ALD GZO films have low resistivity, but the resistivity could be significantly increased after post...