Plants as a green alternative for alcohol preparation from aromatic aldehydes

Suárez-Franco, Gabriela; Hernández-Quiroz, T.; Navarro‐Ocaña, Arturo; Oliart-Ros, Rosa María; Valerio‐Alfaro, Gerardo

doi:10.1007/s12257-009-0207-8

Cited by 18 publications

(6 citation statements)

References 18 publications

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“…These ones for the compounds 2 and 4 shown high chemoselectivity, the carbonyls were unaffected and only the aromatic amine was produced. Chemoselectivity was also observed in some reactions with vegetables 20,26 but only the carbonyl was reduced; also the literature reports the bioreduction of nitroaromatic compounds 21 but with the rather modest yields. Finally, the reaction of substrate 3, with the Linum usitatissimum L. seeds, gave rise to 3-amino-acetophenone (3a) and (S)-1-(3-aminophenyl)ethanol (3b) as products, with values of conversion of 21.6% e 40.5%, respectively.…”

Section: Resultsmentioning

confidence: 78%

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Linseed (Linum usitatissimum L.) as a Biocatalyst for Reduction of Nitroaromatic Compounds

Tavares¹,

Lemos²,

Arriaga³

et al. 2014

Orient. J. Chem.

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Section: Resultsmentioning

confidence: 78%

“…Studies report biotransformation of nitroaromatic compounds using Arracacia xanthorrhiza and Beta vulgaris associated with a microorganism Candida guilliermondii, coconut water which were converted into amines and to the corresponding acetamides. Some plants, as Lens culinaris seeds, are also reported as a biocatalyst for reducing nitro groups [19][20][21] .…”

mentioning

confidence: 99%

Linseed (Linum usitatissimum L.) as a Biocatalyst for Reduction of Nitroaromatic Compounds

Tavares¹,

Lemos²,

Arriaga³

et al. 2014

Orient. J. Chem.

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“…In recent years, biocatalysis, especially plant-derived enzymatic catalysis, has attracted increased interest for the preparation of chiral alcohols. In contrast to a chemical synthesis approach, biocatalysis using plants has several advantages, including being environmentally-friendly, simple procedures, low cost, high efficiency, and excellent enantioselectivity [56]. In addition, plant extracts contain the oxido-reductase, cofactor (NAD(P)H) and its regeneration system, meaning that the enzyme-catalyzed process avoids the addition of the expensive cofactor [57].…”

Section: Potential Use Of the Plants Containing Enzymes Producing Chi...mentioning

confidence: 99%

Plant-Derived Enzymes Producing Chiral Aroma Compounds and Potential Application

Dong¹,

Fan²,

Su³

et al. 2023

Phyton

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Aroma (volatile) compounds play important ecological functions in plants, and also contribute to the quality of plant-derived foods. Moreover, chiral aroma compounds affect their functions in plants and lead to different flavor quality properties. Formations of chiral aroma compounds are due to the presence of enzymes producing these compounds in plants, which are generally involved in the final biosynthetic step of the aroma compounds. Here, we review recent progress in research on the plant-derived enzymes producing chiral aroma compounds, and their changes in response to environmental factors. The chiral aroma enzymes that have been reported produce (R)-linalool, (S)-linalool, (R)-limonene, and (S)-limonene, etc., and these enzymes are found in various plant species. We also discuss the origins of enantioselectivity in the plant-derived enzymes producing chiral aroma compounds and summarize the potential use of plants containing enzymes producing chiral aroma compounds for producing chiral flavors/fragrances.

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“…Chemoselektive Aldehydreduktion in Gegenwart weiterer reduzierbarer funktioneller Gruppen ist mit selektiven ADHs mçglich. [94] Enantioselektive Aldehydreduktionen mit ADHs scheinen zunächst nicht angezeigt. Allerdings ermçglicht die wohl-definierte dreidimensionale Struktur der aktiven Tasche auch die Diskriminierung weiter entfernter Chiralitätszentren.…”

Section: Reduktion Von Aldehydenunclassified

Biokatalytische Reduktionen aus der Sicht eines Chemikers

Hollmann

Opperman²,

Paul

2020

Angewandte Chemie

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Reduktionsreaktionen spielen eine zentrale Rolle in der organischen Chemie zur Synthese chiraler Produkte. Insbesondere Enzyme katalysieren solche Reaktionen in hoher Stereo‐, Regio‐ und Chemoselektivität. Somit eröffnen sie kürzere Alternativrouten zur Synthese von Spezial‐ und Bulkchemikalien. Dieser Aufsatz beschreibt den aktuellen Stand, die Herausforderungen und Möglichkeiten enzymkatalysierter Reduktionen von (konjugierten) Carbonylverbindungen, Aromaten sowie der reduktiven Aminierung.

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Plants as a green alternative for alcohol preparation from aromatic aldehydes

Cited by 18 publications

References 18 publications

Linseed (Linum usitatissimum L.) as a Biocatalyst for Reduction of Nitroaromatic Compounds

Linseed (Linum usitatissimum L.) as a Biocatalyst for Reduction of Nitroaromatic Compounds

Plant-Derived Enzymes Producing Chiral Aroma Compounds and Potential Application

Biokatalytische Reduktionen aus der Sicht eines Chemikers

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