“High-concentration”
and “low-concentration”
bench-scale batch plasma reactors were used to effectively degrade
per- and polyfluoroalkyl substances (PFAS) at a high concentration
(∼100 mg/L) and a low concentration (<1 μg/L), respectively,
in ion exchange (IX) regenerant still bottom (SB) solutions. In the
SBs, numerous PFAS were detected with a wide concentration range (∼0.01
to 100 mg/L; total oxidizable precursors (TOP) ∼4000 to 10000
mg/L). In the “high-concentration” plasma reactor, the
concentrations of PFAS precursors and long-chain perfluoroalkyl acids
(PFAAs) (≥6C for PFSAs and ≥8C for perfluorocarboxylic
acids (PFCAs)) were decreased by >99.9% in 2 h, and short-chain
PFAAs
(<6C for perfluorocarboxylic acids (PFSAs) and <8C PFCAs) were
decreased by >99% in 6 h of treatment. Subsequently, a “low
concentration” plasma reactor was used to remove additional
PFAAs. In this reactor, the addition of CTAB (cetrimonium bromide,
a cationic surfactant) caused short-chain PFAAs, other than PFBA,
to be removed to below detection limits in 90 min of treatment time.
Overall, >99% of the TOP present in SBs was removed during the
treatment.
Fluorine recovery of 47 to 117% was obtained in six SB samples. Energy
requirement (EE/O) for the treatment of PFOA and PFOS from SBs ranged
from 380 to 830 kWh/m3.