“…In turn, our results reveal two different regimes in which HPhPs propagate along mutually orthogonal directions, including the naturally forbidden [001] crystal direction for polaritonic propagation in bare -MoO 3 in the studied spectral range, and exotic intermediate states that unveil the topological origin of the transition, where HPhPs propagate within hyperbolas centered along both the [001] and [100] -MoO 3 directions. Our work opens up stimulating horizons for the investigation of topology-related features in polaritons in vdW materials, such as the existence of edge states (36) , topologically protected states, or the study of nodal points in momentum space protected by symmetries. In addition, extensive and effective control of the propagation of hyperbolic polaritons at the nanoscale is potentially possible via hybridization with plasmon polaritons (37) in various polaritonic heterostructures, thanks to the growing palette of polaritonic vdW materials that sum up to other conventional polaritonic media, such as SiC, aluminum nitride (AlN), or quartz.…”