Platinum(ii) Complex Containing N-(Bis (-2,4-Dimethoxy-Benzyl)carbamothioyl)- 4-Methylbenzamide Ligand: Synthesis,  Crystal Structure, Hirshfeld Surface  Analysis, and Antimicrobial Activity

Solmaz, Ummuhan; Keskin, Ebru; Gümüş, İlkay; Çevik, Pınar Küce; Binzet, Gün; Arslan, Hakan

doi:10.1134/s0022476622010073

Cited by 8 publications

(2 citation statements)

References 41 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In agreement with previous work [ 34 ], the IR frequencies of the ν (C Ar -H) group in the structure of the compounds were monitored in the range of 3078–3113 cm −1 . The data obtained from the FTIR study are compatible with the literature [ [35] , [36] , [37] ] and these data confirmed the structure of the prepared NNN pincer type compounds.…”

Section: Resultssupporting

confidence: 88%

Palladium complexes containing NNN pincer type ligands and their activities in Suzuki-Miyaura cross coupling reaction

Keskin

Arslan

2023

Heliyon

View full text Add to dashboard Cite

Section: Resultssupporting

confidence: 88%

Palladium complexes containing NNN pincer type ligands and their activities in Suzuki-Miyaura cross coupling reaction

Keskin

Arslan

2023

Heliyon

View full text Add to dashboard Cite

“…The bond distances of C1-N1 = 1.325(5), C8-N1 = 1.352(5) Å in the coordinated benzoylthiourea ligand are significantly shorter than the average length of a single C-N bond (1.48 Å). [55][56][57][58] Furthermore, the carbonyl and thiocarbonyl bond distances (O1-C1 = 1.267(5) and S1-C8 = 1.740 (4) Å) of the coordinated ligand are longer than the bond lengths of the corresponding double bond distances of the benzoylthioureas, [58][59][60][61][62][63] and these data show electron delocalization within the chelate ring.…”

Section: Crystallographic Studiesmentioning

confidence: 99%

Ru(II) and Ru(III) complexes containing N‐acylthiourea ligands: Supramolecular structures and synthons, reduction, and reaction pathway of aromatic nitro compounds

Uysal

Solmaz

Arslan

2023

Applied Organom Chemis

View full text Add to dashboard Cite

Four ruthenium complexes {[RuCl(CO)(PPh 3 ) 2 L 1 ], [RuCl(CO)(PPh 3 ) 2 L 2 ],[RuCl 2 (PPh 3 ) 2 L 1 ] and [RuCl 2 (PPh 3 ) 2 L 2 ]} supported with N-acylthiourea-based ligands were synthesized. The compounds prepared were characterized by 1 H NMR, 13 C NMR, elemental analysis, UV-vis, and magnetic susceptibility methods. The characterization of the molecular structure of two ruthenium complexes {[RuCl(CO)(PPh 3 ) 2 L 1 ] and [RuCl 2 (PPh 3 ) 2 L 1 ]} was also performed using the single crystal X-ray diffraction method. Single crystal X-ray analyses indicates the existence of different non-covalent interactions between different parts of the molecules, which led to the formation of three-dimensional supramolecular architectures and synthons. The magnetic susceptibility and UV-vis spectra of the prepared ruthenium complexes propose that they are of low-spin states, where Ru(II) is d 6 and Ru(III) is d 5 low spin. These ruthenium compounds functioned as catalysts for the NaBH 4 -mediated reduction of various nitro compounds. The catalytic results show that the [RuCl 2 (PPh 3 ) 2 L] type complexes exhibit higher catalytic activity than the [RuCl(CO)(PPh 3 ) 2 L] type complexes, and [RuCl 2 (PPh 3 ) 2 L 1 ] has high catalytic selectivity and efficiency in a short time (>99 yield with catalyst loading 0.01 mol in 0.5 h). Furthermore, the catalytic activity of [RuCl 2 (PPh 3 ) 2 L 1 ] was investigated using nitrobenzene as a model substrate to understand the reaction pathway, and this study proved that this nitro reduction proceeds via a direct pathway, with the formation of N-hydroxylamine as the main intermediate followed by the occurrence of aniline.

show abstract

Conversion of monodentate benzoylthiourea palladium(II) complex to bidentate coordination mode: Synthesis, crystal structure and catalytic activity in the Suzuki-Miyaura cross-coupling reaction

Solmaz

İnce

Yılmaz

et al. 2022

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Platinum(ii) Complex Containing N-(Bis (-2,4-Dimethoxy-Benzyl)carbamothioyl)- 4-Methylbenzamide Ligand: Synthesis, Crystal Structure, Hirshfeld Surface Analysis, and Antimicrobial Activity

Cited by 8 publications

References 41 publications

Palladium complexes containing NNN pincer type ligands and their activities in Suzuki-Miyaura cross coupling reaction

Palladium complexes containing NNN pincer type ligands and their activities in Suzuki-Miyaura cross coupling reaction

Ru(II) and Ru(III) complexes containing N‐acylthiourea ligands: Supramolecular structures and synthons, reduction, and reaction pathway of aromatic nitro compounds

Conversion of monodentate benzoylthiourea palladium(II) complex to bidentate coordination mode: Synthesis, crystal structure and catalytic activity in the Suzuki-Miyaura cross-coupling reaction

Contact Info

Product

Resources

About