2023
DOI: 10.1002/advs.202205479
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Polar Nitride Perovskite LaWN3‐δ with Orthorhombic Structure

Abstract: Nitride perovskite LaWN3 has been predicted to be a promising ferroelectric material with unique properties for diverse applications. However, due to the challenging sample preparation at ambient pressure, the crystal structure of this nitride remains unsolved, which results in many ambiguities in its properties. Here, the authors report a comprehensive study of LaWN3 based on high‐quality samples synthesized by a high‐pressure method, leading to a definitive resolution of its crystal structure involving nitro… Show more

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Cited by 7 publications
(1 citation statement)
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References 72 publications
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“…It is essential to note that X-ray photoelectron spectroscopy (XPS) is a near surface analysis technique and the accuracy of the results is highly dependent on instrument calibration and sample preparation. 183,184 The quantitative determination of N content can also be obtained through Rietveld analysis, which involves fitting crystal structure parameters to acquire precise crystallographic information. 185…”
Section: Mns Electrocatalystsmentioning
confidence: 99%
“…It is essential to note that X-ray photoelectron spectroscopy (XPS) is a near surface analysis technique and the accuracy of the results is highly dependent on instrument calibration and sample preparation. 183,184 The quantitative determination of N content can also be obtained through Rietveld analysis, which involves fitting crystal structure parameters to acquire precise crystallographic information. 185…”
Section: Mns Electrocatalystsmentioning
confidence: 99%