The dynamics of polarization switching have been investigated over extremely broad time (10−8<t<102 s) and field ranges for (001)c, (110)c, and (111)c-oriented Pb(Zn1/3Nb2/3)O3–4.5%PbTiO3 crystals. The results demonstrate the presence of broad relaxation time distributions that can extend over a decade(s) in orders of magnitude in time, and which sharpen significantly with increasing field. The polarization transients have been fit to stretched exponential functions, which are typical of disordered systems.