Poly[bis(μ-hemihydrogen 2-phenylquinoline-4-carboxylato-κ²N,O)silver(I)]

Abstract

In the title compound, [Ag(C16H10.5NO2)2], the AgI cation (site symmetry 2) is coordinated by two N atoms in a near-linear AgN2 arrangement. Two carboxyl­ate O atoms from two additional 2-phenyl­quinoline-4-carboxyl­ate ligands form long Ag—O bonds [2.6585 (17) Å], resulting in a distorted square-planar arrangement. The bridging ligands result in infinite corrugated sheets propagating in (010). An O—H⋯O hydrogen bond, disordered about a twofold axis, completes the structure.

A three-dimensional supramolecular framework of silver(I), 2-phenylquinoline-4-carboxylate and 4,4′-bipyridine

“…However, the use of the isonicotinic acid analogue 2-phenylquinoline-4-carboxylic acid (HL) to construct metalorganic frameworks has been less thoroughly investigated to date (Qin et al, 2002;Shen et al, 2007;Wang et al, 2010;Li et al, 2011;Zhang et al, 2009). The 2-phenylquinoline-4-carboxylate ligand, L, was selected based on the following considerations.…”

“…Due to the introduction of 4,4 0 -bipy as a second ligand into the Ag-L system, complex (I) displays a distinctly different structure from poly[bis(-hemihydrogen 2-phenylquinoline-4-carboxylato-2 N,O)silver(I)], (II) (Zhang et al, 2009). Although as a potential coordinating group, unlike (II), the quinoline N atom does not coordinate to the Ag I cation in (I), but instead forms hydrogen-bonding interactions with solvent water molecule O2W.…”