Poly[[bis[μ₂-1,3-bis(phenylsulfanyl)propane-κ²S:S′]silver(I)] hexafluoridoantimonate diethyl ether hemisolvate]

Abstract

The title compound, {[Ag(C15H16S2)2]SbF6·0.5C4H10O}n, was obtained from the self‐assembly of AgSbF6 and 1,3‐bis(phenylsulfanyl)propane. Each AgI ion is coordinated by four S atoms from different ligands, forming a distorted tethrahedral geometry. Each ligand links adjacent AgI ions, forming an extended two‐dimensional grid‐like framework. SbF6− ions, which are incorporated into the cavities of the network, complete and stabilize the structure. One of the phenyl rings is disordered over two sites, the ratio of occupancies being 0.508 (4):0.492 (4).