In the title structure, C22H30S2, L10, the asymmetric unit contains two independent mol­ecules, both of which lie on crystallographic inversion centers, and the aliphatic chains are in the all‐trans conformation. The crystal structure is stabilized by a combination of van der Waals forces and weak C—H⋯π(arene) inter­actions.

The title compound, trans‐[PdCl2(PhSCH2SPh)2], crystallizes with two half‐mol­ecules in the asymmetric unit and each independent mol­ecule lies about a crystallographic inversion center. In each mol­ecule, one S atom of the bis­(phenyl­sulfan­yl)methane ligand is coordinated to the Pd atom while the second S atom of the same ligand is uncoordinated.

In the title crystal structure, C14H14S2, L2, the mol­ecules lie on crystallographic inversion centers. The phen­yl rings are nearly perpendicular to the planar S—C—C—S group of atoms.

The title compound, {[Ag(C15H16S2)2]SbF6·0.5C4H10O}n, was obtained from the self‐assembly of AgSbF6 and 1,3‐bis(phenylsulfanyl)propane. Each AgI ion is coordinated by four S atoms from different ligands, forming a distorted tethrahedral geometry. Each ligand links adjacent AgI ions, forming an extended two‐dimensional grid‐like framework. SbF6− ions, which are incorporated into the cavities of the network, complete and stabilize the structure. One of the phenyl rings is disordered over two sites, the ratio of occupancies being 0.508 (4):0.492 (4).

Key indicatorsSingle-crystal X-ray study T = 100 K Mean (C-C) = 0.003 Å R factor = 0.054 wR factor = 0.166 Data-to-parameter ratio = 14.7For details of how these key indicators were automatically derived from the article, see