The emerging mega city of Lahore has been progressing by leaps and bounds in lasttwo decades which is directly related to an immense increase of number of vehicles and powergeneration systems using fossil fuels. The present study entails the quantification and evaluation ofpotential risk due to Polycyclic Aromatic Hydrocarbons (PAHs) which is one of the known organicpollutants from vehicular, power generation system’s exhaust and other industrial activities. Thesamples of Total Suspended Particulate Matters (TSPM) were collected from various urbanized sitespresent at Badami Bagh, Lahore, Pakistan for the estimation of polycyclic aromatic hydrocarbons. Thetechnique used for quantification of PAH’s was Gas Chromatography. The concentration of mean totalof PAH was 746.60 ng/m3. Dibenzo(a,h) Anthracene was found to be in highest concentration of142.35 ng/m3 among all the polycyclic aromatic hydrocarbons under investigation.