2021
DOI: 10.1002/cjoc.202000536
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Polyhedral Oligomeric Silsesquioxanes (POSS)‐based Hybrid Materials: Molecular Design, Solution Self‐Assembly and Biomedical Applications

Abstract: Owing to the tremendous advantages and unique well‐defined nanoscale structure, polyhedral oligomeric silsesquioxanes (POSS) have received considerable interest in the design of novel organic‐inorganic hybrid nanomaterials with all manner of prominent capabilities, which is recognized as a new generation of promising materials for advanced applications of material science, engineering science and biomedical fields. Benefitting from the recent progress in combination of controlled/living polymerization and emer… Show more

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Cited by 36 publications
(22 citation statements)
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References 140 publications
(180 reference statements)
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“…The measured XRD patterns were similar to the XRD patterns of the POSS mixture and LPSQ [ 58 ]. In addition, EPSQ d-spacing 2 showed a stronger intensity than the XRD data from other studies with similar structures [ 29 ]. This is because the synthesized polymer has a higher region regularity than the polymers reported in the literature.…”
Section: Resultsmentioning
confidence: 66%
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“…The measured XRD patterns were similar to the XRD patterns of the POSS mixture and LPSQ [ 58 ]. In addition, EPSQ d-spacing 2 showed a stronger intensity than the XRD data from other studies with similar structures [ 29 ]. This is because the synthesized polymer has a higher region regularity than the polymers reported in the literature.…”
Section: Resultsmentioning
confidence: 66%
“…POSS and LPSQ have a chemical structure of (RSiO 1.5 )n consisting of strong Si–O–Si bonding [ 23 , 27 ]. POSS is an oligomer with a chemical structure (RSiO 1.5 )n (N = 6, 8, 10, 12) [ 28 , 29 ]. The POSS structure shows high thermal stability owing to its three-dimensional cage structure [ 30 , 31 ].…”
Section: Introductionmentioning
confidence: 99%
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“…There has been a considerable attention drawn to the applications of POSS containing drug conjugates, since POSS is regarded as the next generation of materials in biomedical fields [19,[55][56][57]. Compared to functionalized silica as drug delivery system, silsesquioxanes present much more uniform size (~1.5 nm).…”
Section: Silsesquioxanes-platinum Drugs Conjugatesmentioning
confidence: 99%
“…In the past decades, POSS have been used as building blocks, crosslinkers, and nanofillers to afford hybrid materials with improved stability, mechanical properties and chemical resistance [10]. POSS have great potential in various fields such as catalysis, sensing, photoelectronic, energy, and biomedicine [3,[11][12][13][14][15]. In this review, we will emphasize the most recent advances on the use of POSS in biomedicine, with particular focus on drug delivery, photodynamic therapy and bioimaging.…”
Section: Introductionmentioning
confidence: 99%