Citation for published item: ¦ lssonD vF yF nd zlewskiD wrek nd oertsD eF nd wsutniD eF nd voveD qF hF nd grossD qF rF nd floorD hF nd uyD eF tF nd oolhouseD eF hF nd wsutniD eF nd sudD eF @PHHQA 9yrienttion nd solvtohromism of dyes in liquid rystlsF9D woleulr rystls nd liquid rystlsFD RHP @IAF ppF RQESQF Further information on publisher's website: httpXGGdxFdoiForgGIHFIHVHGURRVITTVS
Use policyThe full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details. The orientation and solvatochromism of some dye molecules in a liquid crystal have been investigated. Interactions with the host and the structure of the dye molecule affect the macroscopic alignment of dichroic dye molecules in a liquid crystal. It was observed that some dye molecules show a large bathochromic shift of their absorption maxima in the liquid crystal host relative to the situation in isotropic solvents. It is suggested that this is due to the occurrence of a much weaker reaction field in the anisotropic, rigid host. These dye molecules show little or no apparent order in the anisotropic host despite the observation of a reduction in the electro optic switching time when the dye is present. The highest degree of macroscopic alignment was observed for a merocyanine compound, which showed the smallest solvatochromic shift in the liquid crystal host. These results are discussed in terms of the steric, dipolar and hydrogen bond interactions between the guest and the host.