Polymeric stationary phase, based on (R,R)‐tartramide and bisphenol S, with potential chiral properties

Abstract

A new polymeric stationary phase with potential chiral properties, obtained by the chemical modification of the parent copolymer of dimethacrylate esters of bisphenol S and divinylbenzene, is presented. Hydroxyl functional groups present in the copolymer chemical structure are blocked by optically active selectors of (R,R)‐tartramide derivatives. The influence of the chemical modification of the parent copolymer on its porous structure has been studied. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2566–2574, 2004

Synthesis, modification, and porous properties of new glycidyl methacrylate copolymers

“…Synthesis of polymeric microspheres based on (meth)acrylate derivatives of aromatic diols and their practical use as column packing in high performance liquid chromatography (HPLC) and solid phase extraction (SPE) technique has been the subject of our previous research works 24–26. As a comonomer, divinylbenzene was used.…”