Polymerization of diphenyldiacetylene and of tolan in the presence of carbonyl cobalt complexes. Structure and properties of the polymer

Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide by a Polymerized Film of an Alkynyl‐Substituted Rhenium(I) Complex

“…Peaks 1 and 4, attributed to the monomer ligand, decrease in intensity with the increasing number of scans, which suggests a ligand‐based polymerization of 1 . The polymerization is assumed to proceed through radical coupling between two electrogenerated radical species as reported previously for similar systems,19, 21 although alternative routes cannot be excluded owing to the presence of metal carbonyl species 23. Furthermore, the maximum of the first reduction wave shifts towards more negative potentials with the increasing number of scans.…”

Polymers of Phenyldiacetylenes – Functional Thermostable Additions to Industrial Resins

“…Anionic homo-and copolymerization of DPD and DEB were performed in polar solvents in the presence of n-BuLi [14][15][16][17][18][19]. All synthesized polyconjugated polymers were yellow or brown powders, well-soluble in organic solvents.…”

“…Synthesis of homopolymers of DPD [14,15], DEB [16,17] and their random copolymers [18,19] under mild conditions (anionic initiators, temperature below 333 К) allowed obtaining for systematical studies the polymers characterized by:…”

“…3). Upon increasing the temperature, the decrease in rate of mass loss and formation of appreciable "coke" residue were noticed [17].…”

“…• Addition of poly-PA practically did not increase thermooxidation stability of solidified TGM-3 (exp. [16][17][18].…”