Polymerization of vinylpyridinium salts. IX. Preparation of monomeric salt pairs

Polymer Alloys, Blends, and Ionomers

“…The ionomers prepared by this route, however, were reported to be "blocky" with regard to the incorporation of the sulfonated styrene monomer. Salamone et al (71)(72)(73)(74)(75)(76) prepared ionomers based on the copolymerization of a neutral monomer, such as styrene, methyl methacrylate, or n-butyl acrylate, with a cationic-anionic monomer pair, 3-methacrylamidopropyltrimethylammonium 2-acrylamide-2-methylpropane sulfonate.…”

Copolymerization Behavior of Acid‐Base Monomer Systems and Properties of their Corresponding Polymers

“…Polyelectrolytes obtained from this reaction and similar products from polymerization of mono-or bifunctional organic salts (i.e., with a polymerizable double bond on just one or both components) [2][3][4][5][6][7][8] have been discussed as solid-state ion and proton conductors and novel polymer electrolytes for batteries and fuel cells [1-VIm/vinylsulfonic acid, 1-VIm/3-sulfopropyl acrylate, [1] vinylpyrrolidone/ 2-acrylamido-2-methyl-1-propanesulfonic acid (APSA), [9] and imidazole/APSA [10] ]. Other authors also suggest applications of zwitterionic ampholytic ionomers as polymeric surfactants [11,12] or of poly(ILs) as gas storage media with improved capacity, e.g., for CO 2 , [13] for producing organic conducting dispersions [14] or as stabilizers and phase transfer agents for nanoscaled objects.…”

“…[15] Similar systems of several pyridinium salts [4-vinylpyridine (4-VP)/vinylsulfonic acid, 4-VP/APSA, and 4-VP/ p-styrenesulfonic acid] were also investigated, but in this case the authors emphasized explaining an observed autopolymerization reaction. [6,7] More studies on the preparation of amphoteric polymers can also be found in the…”

Copolymerization of 2‐Acrylamido‐2‐methyl‐1‐propanesulfonic Acid and 1‐Vinylimidazole in Ethanol

“…Polyelectrolytes such as 1‐vinylimidazole (1‐VIm)/vinylsulfonic acid, 1‐VIm/3‐sulfopropyl acrylate, vinylpyrrolidone/2‐acrylamido‐2‐methyl‐1‐propanesulfonic acid (AMPS), and imidazole/AMPS obtained from the polymerization of mono‐ or bifunctional organic salts and acidic and/ or basic monomers, have been developed as solid‐state ion and proton conductors and novel polymer electrolytes for batteries and fuel cells 1–12. Proposed applications for these zwitterionic ampholytic ionomers include: use as polymeric surfactants,13, 14 gas storing poly(ionic liquid)s,15 for producing organic conducting dispersions,16 and as stabilizer and phase transfer agents for nanoscale objects 17.…”

“…Extensive studies have been reported by Salamone,5, 6, 21, 22 Kabanov23 and Tsuchida24 on the preparation of amphoteric polymers. An interesting example by Kurenkov et al described the reaction behavior of AMPS, its salts and copolymerization with basic monomers, e.g.…”