Polymethylhydrosiloxane

Lavis, Jérôme M.; Maleczka, Robert E.; Chandrasekaran, Vijayanand; Collier, S. J.

doi:10.1002/047084289x.rn00062.pub2

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Introduction1

Optimization Of the No-reduction Of 1a Using Copper Hydride ...1

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2022

2024

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Cited by 2 publications

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References 218 publications

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“…PMHS was particularly appealing, being a by-product of the silicon industry that has lower price, higher availability and greener footprint than most other silane options. 34,35 We also observed that addition of tert-butanol to the reaction mixture significantly improved reactivity (entry 5-6 vs. 3-4), although without effect on selectivity. We rationalized this as a competition between the alcohol and the amino group of 2a in ligating the copper catalyst after the reduction step, thus the alcohol facilitates product elimination from the metal.…”

Section: Introductionmentioning

confidence: 59%

See 1 more Smart Citation

Continuous-flow copper hydride-catalyzed reduction of 2,1-benzoisoxazoles

Cavedon,

Mear,

Croke

et al. 2024

React. Chem. Eng.

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Section: Introductionmentioning

confidence: 59%

“…PMHS was particularly appealing, being a by-product of the silicon industry that has lower price, higher availability and greener footprint than most other silane options. 34,35…”

Section: Optimization Of the No-reduction Of 1a Using Copper Hydride ...mentioning

confidence: 99%