Polypyrrole/SnCl2 modified bacterial cellulose electrodes with high areal capacitance for flexible supercapacitors

Sun, Yan; Yang, Yuan; Fan, Lingling; Zheng, Wenfeng; Ye, Dezhan; Xu, Jie

doi:10.1016/j.carbpol.2022.119679

Cited by 23 publications

(9 citation statements)

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“…Each cellulose sample shows a characteristic broad peak at 3372 cm –1 for O–H stretching vibration. The distinctive peaks at 2905, 1643, and 1066 cm –1 are due to the −CH 2 stretching vibration, CO stretching vibration, and C–O–C stretching of pyranose, respectively . C(E) shows three extra sharp peaks due to the presence of clay particles at 3678 cm –1 for O–H stretching and at 669 and 535 cm –1 for Si–O stretching .…”

Section: Resultsmentioning

confidence: 99%

Polyindole-Stabilized Nanocellulose-Wrapped Ti₃C₂T_x (MXene) Nanocomposite for Asymmetric Supercapacitor Devices

Acharya

Maity

et al. 2023

ACS Appl. Energy Mater.

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Nanocellulose fiber-based composites have been studied as supercapacitor electrodes due to their mechanical and chemical stability. The non-conductivity of nanocellulose has been tuned by MXene, a 2D nanomaterial, and its composites, for use as electrode materials for energy storage applications. This work reports the synthesis of polyindole-stabilized nanocellulose-wrapped MXene nanocomposite-based electrodes for supercapacitors. Nanocellulose, extracted from various renewable biowastes, is wrapped around MXene nanosheets to prevent the restacking of Ti3C2T x layers with the structure being stabilized with polyindole. The morphology, structure, and chemical composition were confirmed with field-emission scanning electron microscopy (FESEM), X-ray diffraction, and X-ray photoelectron spectroscopy, respectively. Morphological analysis, by FESEM and transmission electron microscopy, confirmed successful synthesis of the ternary nanocomposites. The concentration of Ti3C2T x and nanocellulose was optimized to get best possible electrochemical performance of the electrodes. The best electrochemical performance was achieved with an MXene-grass cellulose-polyindole-1:1 composite [MPC(G)-1:1] with a specific capacitance of 858 F g–1 at 1 A g–1, in a three-electrode setup. An asymmetric device fabricated with developed nanocomposites as the cathode delivered a specific capacitance of 90 F g–1 and an energy density of 40.5 W h kg–1 at 1 A g–1 with 94.1% capacitance retention after 10,000 cycles. This study established the conversion of biowaste to efficient supercapacitor electrodes via a facile low-cost process.

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Section: Resultsmentioning

confidence: 99%

Polyindole-Stabilized Nanocellulose-Wrapped Ti₃C₂T_x (MXene) Nanocomposite for Asymmetric Supercapacitor Devices

Acharya

Maity

et al. 2023

ACS Appl. Energy Mater.

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Section: Recent Bc‐based Macroscopic Materials For Advanced Applicationsmentioning

confidence: 99%

“…Their prepared PPy@SBC electrode has excellent cycling stability (86.8% at 10 mA cm −2 for 10 000 cycles) and an ideal 83.1% capacitance retention at a current density of 5.0 mA cm −2 (Figure 17E). [182] Other components can be introduced during electrode preparation, such as conductive polymers (polyethylenedioxythiophene, [183] polyaniline, [178] polypyrrole [184] ) or metal oxides. [185] The carbonization of BC (CBC) can be used to improve the electrical activity of BC nanofibers.…”

Section: Bc-based 3d Electrodes For Electrochemical Energy Storagementioning

confidence: 99%

“…No capacitance degradation (5000) [179] BC/HRGO 65.9 F g −1 (0.4 A g −1 ) 88% (5000) [181] CBC 352 F g −1 (1 A g −1 ) 100% (65 000) [186] MXene/BC composite electrodes 111.5 mF cm −2 72% (5000) [189] BC/PEDOT 127.6 mF cm −2 (0.5A cm −2 ) 92.8% (5000) [183] BC/GE/PANI 645 F g −1 (1 A g −1 ) 82.2% (1000) [178] PPy@SBC 5718 mF cm −2 (0.5 mA cm −2 ) 86.8% (10 000) [182] NCNF ≈224 F g −1 (0.5 A g −1 ) 97% (10 000) [188] r-Bi 2 O 3 /GN/BC 6675 mF cm −2 (1 mA cm −2 ) 88% (3000) [185] NiMn-LDH/PPy/BC 1427 F g −1 (1A g −1 ) - [184] Abbreviations: GN, graphene nanosheets; HRGO, holey graphene oxide; GE, graphene; NiMn-LDH, bimetallic hydroxide.…”

Section: Bc-based 3d Electrodes For Electrochemical Energy Storagementioning

confidence: 99%

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Insights into Hierarchical Structure–Property–Application Relationships of Advanced Bacterial Cellulose Materials

Chen

et al. 2023

Adv Funct Materials

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Bacterial cellulose (BC) is an environmentally friendly biomaterial that is widely investigated because it possesses a unique hierarchical nanofiber network structure as well as extraordinary performance. In this review, the formation of the BC hierarchical nanofiber network structure from the perspective of biosynthesis is illustrated based on its basic chemical and crystal structure. Moreover, the design and processing of BC-based advanced materials through biosynthesis, physical, and/or chemical modification are also reviewed. The intrinsic characteristics of BC, derived from its hierarchical structure, are analyzed to understand its structure-property-application relationships. The applications of advanced BC-based materials are reviewed, such as high-strength structural materials utilizing the properties of nanofibers, energy conversion and storage, bioelectronic interfaces, environmental remediation, and thermal management applications utilizing the ion transport properties and 3D network structures of these materials. In addition, the authors also offer their opinions and potential future research directions for sustainably developing BC-based materials.

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“…After that, Ummartyotin et al [12] also found that modified bacterial cellulose by grafting with strontian ion can be effectively enhanced the electroactive properties. Recently, in 2022, Sun et al [13] developed polypyrrole and SnCl2 modified bacterial cellulose as a flexible electrode for supercapacitor. It exhibited a capacitance of 5718 mF⸳cm -2 at a current density of 0.5 mA⸳cm -2 .…”

Section: Introductionmentioning

confidence: 99%

Development of FexOy particle onto bacterial cellulose network by forced hydrolysis and its electrical conductivity

et al. 2022

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FexOy particle and bacterial cellulose composite sheet was successfully prepared by forced hydrolysis. The presence of Fe3+ ions in bacterial cellulose suspension significantly provided the positive charge due to electrostatic force as reported by Zeta potential. With the pH of 12 of bacterial cellulose suspension, particle was nucleated between bacterial cellulose networks. Fourier transform infrared exhibited Fe-O stretching. X-ray diffraction reported that the mixture of Fe2O3 and Fe3O4 was existed onto bacterial cellulose composite. Scanning electron microscope reported that FexOy particle was randomly distributed in bacterial cellulose network. Intensity of Fe was qualitatively observed by energy dispersive analysis. With the existence of FexOy particle, the composite illustrated the inferiority of thermal stability of 150℃. Furthermore, it was noted that the resistivity was reduced with respect to increment of FexOy particle, suggesting that electrical conductivity was then enhanced. It was remarkable to note that FexOy particle and bacterial cellulose composite sheet prepared from forced hydrolysis showed the excellent properties as a candidate for flexible electrode.

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Polypyrrole/SnCl2 modified bacterial cellulose electrodes with high areal capacitance for flexible supercapacitors

Cited by 23 publications

References 50 publications

Polyindole-Stabilized Nanocellulose-Wrapped Ti₃C₂T_x (MXene) Nanocomposite for Asymmetric Supercapacitor Devices

Polyindole-Stabilized Nanocellulose-Wrapped Ti₃C₂T_x (MXene) Nanocomposite for Asymmetric Supercapacitor Devices

Insights into Hierarchical Structure–Property–Application Relationships of Advanced Bacterial Cellulose Materials

Development of FexOy particle onto bacterial cellulose network by forced hydrolysis and its electrical conductivity

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Polypyrrole/SnCl2 modified bacterial cellulose electrodes with high areal capacitance for flexible supercapacitors

Cited by 23 publications

References 50 publications

Polyindole-Stabilized Nanocellulose-Wrapped Ti3C2Tx (MXene) Nanocomposite for Asymmetric Supercapacitor Devices

Polyindole-Stabilized Nanocellulose-Wrapped Ti3C2Tx (MXene) Nanocomposite for Asymmetric Supercapacitor Devices

Insights into Hierarchical Structure–Property–Application Relationships of Advanced Bacterial Cellulose Materials

Development of FexOy particle onto bacterial cellulose network by forced hydrolysis and its electrical conductivity

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Polyindole-Stabilized Nanocellulose-Wrapped Ti₃C₂T_x (MXene) Nanocomposite for Asymmetric Supercapacitor Devices

Polyindole-Stabilized Nanocellulose-Wrapped Ti₃C₂T_x (MXene) Nanocomposite for Asymmetric Supercapacitor Devices