Polypyrrole/tannin biobased nanocomposite with enhanced electrochemical and physical properties

Abdi, Mahnaz M.; Azli, Nur Farhana Waheeda Mohd; Lim, Hong Ngee; Tahir, Paridah Md.; Karimi, Gholamreza; Hoong, Yeoh Beng; Khorram, Mohammad

doi:10.1039/c7ra13378b

Cited by 27 publications

(12 citation statements)

References 32 publications

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“…The bands at 914, 795, and 1185 cm −1 are indicated the CH vibration. The bipolaron state of PPy is proved through observation of the peaks located at 1185 and 914 cm −1 wavelengths 22,32‐34 …”

Section: Resultsmentioning

confidence: 99%

Polypyrrole‐aided surface decoration of graphene oxide nanosheets as fillers for poly(ether‐ b ‐amid) mixed matrix membranes to enhance CO ₂ capture

Asghari

Saadatmandi

Parnian³

2021

Int J Energy Res

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Summary Modified graphene oxide (GO) nanosheets as fillers within poly(ether‐b‐amid) (PEBA) copolymer as matrix were used for mixed matrix membranes (MMMs) fabrication to improve CO2 capture. The GO nanosheets were modified by polypyrrole (PPy) and zinc cations. The former that have conjugated N‐containing groups provided a high degree of affinity toward CO2, and the latter has facilitated the gas molecules transport through the gas channel passages. The different modified GO nanosheets were characterized by HRTEM, FT‐IR, FESEM, XRD, and XPS analyses. Also, the FT‐IR, XRD, AFM, and SEM methods were used for the structural and morphological characterizations of the prepared MMMs with 0.1 wt% of the nanofiller. Gas permeation tests for CH4, N2, and CO2 were then performed for all prepared membranes. Compared to the neat PEBA membrane, the selectivity of both CO2/CH4 and CO2/N2 for PEBA‐GO‐PPy membrane increased up to 62% and 51% and for the PEBA‐GO‐PPy‐Zn membrane increased up to 58% and 56%, respectively. Furthermore, the PEBA‐GO‐PPy‐Zn disclosed a 10% increase in permeability of CO2 than the neat membrane. For PEBA‐GO‐PPy MMM, the permeability of CO2 was 122.4 Barrer, and the selectivity of CO2/CH4 and CO2/N2 was 29.8 and 122.5, respectively. Moreover, the gas separation results for PEBA‐GO‐PPy‐Zn MMM were about 131.8 Barrer for CO2 permeability and 30.7 and 119.2 for CO2/CH4 and CO2/N2 selectivities, respectively. Besides, the CO2/N2 selectivity of PEBA‐GO‐PPy and PEBA‐GO‐PPy‐Zn overcomes the Robeson's upper bound.

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Section: Resultsmentioning

confidence: 99%

Polypyrrole‐aided surface decoration of graphene oxide nanosheets as fillers for poly(ether‐ b ‐amid) mixed matrix membranes to enhance CO ₂ capture

Asghari

Saadatmandi

Parnian³

2021

Int J Energy Res

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“…The stock solution was prepared freshly for each experimental run time. Based on our prior work and CV results, 18 the nanocomposite of PPy/TA/CTAB prepared from solution containing Py (0.1 M), TA (0.0066 M), APS (0.1 M), and CTAB (6 CMC) as follow: TA solution were prepared by dissolving TA powder in DIW until TA was homogenized completely and the solution of Py‐CTAB was prepared by adding 6 CMC of CTAB to 0.1 M solution of pyrrole in DIW. The CMC of CTAB is 0.87 mM 19 .…”

Section: Methodsmentioning

confidence: 99%

“…Condensed TAs were prepared at the Institute of Tropical Forestry and Forest Products, Universiti Putra Malaysia as the literature reported from our research group earlier. 18 Pyrrole, ammonium persulfate (NH 4 ) 2 S 2 O 8 (APS), and cetyltrimethylammonium bromide (CTAB), were provided by Sigma-Aldrich Chemie GmbH. The pyrrole monomer was purified by distillation at a temperature of 128 C and then stored in the refrigerator.…”

Section: Materials and Characterizationmentioning

confidence: 99%

“…Our research group has been worked on the synthesis of conducting polymer nanostructures using surfactants and biomolecules. In current work, in order to enhance the physico‐chemical properties of polypyrrole, polymerization was done in the presence of a biopolymer (TA) and a cationic surfactant (CTAB) and in our previous work the best composition to obtain the highest electron transferring rate was achieved 18 . So, in the current research the nanocomposite of PPy/TA/CTAB with the highest electron transferring rate was used for the fabrication of DA biosensor.…”

Section: Introductionmentioning

confidence: 99%

“…In current work, in order to enhance the physico-chemical properties of polypyrrole, polymerization was done in the presence of a biopolymer (TA) and a cationic surfactant (CTAB) and in our previous work the best composition to obtain the highest electron transferring rate was achieved. 18 So, in the current research the nanocomposite of PPy/TA/CTAB with the highest electron transferring rate was used for the fabrication of DA biosensor. Cationic surfactant of CTAB played an important role as a soft template to prepare a nanostructured compound for developing a high porosity substrate, enhancing electron transferring rate in the compound.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Nonenzymatic dopamine biosensor based on tannin nanocomposite

Abdi

Azli

Chaibakhsh

et al. 2021

Journal of Polymer Science

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A dopamine (DA) biosensor was developed based on polypyrrole/tannin/cetyltrimethylammonium bromide (PPy/TA/CTAB) nanocomposite and central composite rotatable design (CCRD) was employed for the optimization of conditions. Chemical polymerization of the PPy/TA in the presence of a cationic surfactant, CTAB, reduced the particle size of composite and a rod‐like structure with a lumpy surface and high porosity was observed for nanocomposite justifying the highest current response for the modified electrode. Amperometry and differential pulse voltammetry analyses were applied for all electrochemical measurements and DA detection in the range of 0.5–100 μM. The good adhesion of nanocomposite on the electrode surface, as well as porosity and high surface area of the modified electrode, enhanced the diffusion of DA molecules inside the matrix. Amperometry analysis of the Screen printed carbon electrode/PPy/TA/CTAB modified electrode displayed a good sensitivity of 0.039 μA (μM)−1 toward DA with the limit of detection of 2.9 × 10–7 M. The modified biosensor also excludes the interfering species of ascorbic acid and uric acid which makes this sensor appropriate for DA determination. The proposed biosensor showed an acceptable reproducibility and repeatability with low relative standard deviations of 4.8% and 4.4%, respectively.

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Engineering of Crosslinked Network and Functional Interlayer to Boost Cathode Performance of Tannin for Potassium Metal Batteries

Luo

Tang

Jiang

et al. 2022

Adv Funct Materials

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Potassium metal batteries (PMBs) are a compelling technology for large-scale energy storage due to the abundance of potassium resources and high energy density. A vital obstacle to construct high-performance PMBs is developing superior cathode materials. Tannin, a plant polyphenol, holding many active sites for redox reactions, is an auspicious high-capacity cathode. However, the relatively poor conductivity and slight solubility in electrolyte deteriorate its capacity and cycle stability. Herein, the tannin is activated through a crosslinking reaction with polyaniline to obtain a composite cathode (i.e., ATN). It exhibits a high initial capacity of 172 mAh g −1 at 50 mA g −1 , based on the electrochemical reaction mechanisms of embedding/releasing of K + on CO and PF 6 − on NH. Moreover, to improve the cycling performance, a graphene oxide modified separator is developed to effectively retard the ATN shuttle. As a result, the capacity retention is significantly enhanced, for example, 82% over 300 cycles at 50 mA g −1 . From a practical aspect, a full PMB of K@K x P y ||ATN is built up, displaying high energy/power density and superior cycling stability, which is a step forward in the development of PMBs.

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Polypyrrole/tannin biobased nanocomposite with enhanced electrochemical and physical properties

Abstract: Tannin (TA) extracted from Acacia mangium and a cationic surfactant, cetyltrimethylammonium bromide (CTAB), were used to modify and enhance the physical and electrochemical properties of polypyrrole (PPy) composite.

Cited by 27 publications

References 32 publications

Polypyrrole‐aided surface decoration of graphene oxide nanosheets as fillers for poly(ether‐ b ‐amid) mixed matrix membranes to enhance CO ₂ capture

Polypyrrole‐aided surface decoration of graphene oxide nanosheets as fillers for poly(ether‐ b ‐amid) mixed matrix membranes to enhance CO ₂ capture

Nonenzymatic dopamine biosensor based on tannin nanocomposite

Engineering of Crosslinked Network and Functional Interlayer to Boost Cathode Performance of Tannin for Potassium Metal Batteries

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Polypyrrole/tannin biobased nanocomposite with enhanced electrochemical and physical properties

Abstract: Tannin (TA) extracted from Acacia mangium and a cationic surfactant, cetyltrimethylammonium bromide (CTAB), were used to modify and enhance the physical and electrochemical properties of polypyrrole (PPy) composite.

Cited by 27 publications

References 32 publications

Polypyrrole‐aided surface decoration of graphene oxide nanosheets as fillers for poly(ether‐ b ‐amid) mixed matrix membranes to enhance CO 2 capture

Polypyrrole‐aided surface decoration of graphene oxide nanosheets as fillers for poly(ether‐ b ‐amid) mixed matrix membranes to enhance CO 2 capture

Nonenzymatic dopamine biosensor based on tannin nanocomposite

Engineering of Crosslinked Network and Functional Interlayer to Boost Cathode Performance of Tannin for Potassium Metal Batteries

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Product

Resources

About

Polypyrrole‐aided surface decoration of graphene oxide nanosheets as fillers for poly(ether‐ b ‐amid) mixed matrix membranes to enhance CO ₂ capture

Polypyrrole‐aided surface decoration of graphene oxide nanosheets as fillers for poly(ether‐ b ‐amid) mixed matrix membranes to enhance CO ₂ capture